{"id":"W4214636979","doi":"10.1139/cjc-2021-0320","title":"A new synthesis of (<i>Z</i>,<i>Z</i>)-11,11-dimethoxy-6,9-heneicosadiene and 2-((<i>Z</i>,<i>Z</i>)-1,4-decadienyl)-2-<i><sup>n</sup></i>decyl-1,3-dioxolane, precursors of (<i>Z</i>,<i>Z</i>)-6,9-heneicosadien-11-one, a pheromone component of the whitemarked tussock moth, <i>Orgyia leucostigma</i> (J.E. Smith) (Lepidoptera: Erebidae)","year":2022,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Insect Pheromone Research and Control","field":"Agricultural and Biological Sciences","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Resources Canada; Canadian Forest Service; University of New Brunswick","funders":"Natural Resources Canada; Atlantic Canada Opportunities Agency; Government of Canada","keywords":"Chemistry; Sex pheromone; Stereochemistry; Diene; Bromide; Alkyne; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.002462211,0.000924668,0.002254065,0.0002140021,0.0007671489,0.0001225582,0.002958906,0.0004153099,0.001449583],"category_scores_gemma":[0.0006646948,0.0005457565,0.001194763,0.001867322,0.0008983808,0.00038746,0.0005352182,0.001198073,0.00000266091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003780313,"about_ca_system_score_gemma":0.001775556,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0185442,"about_ca_topic_score_gemma":0.01128967,"domain_scores_codex":[0.991702,0.001081325,0.002715361,0.0009266302,0.001892689,0.001681947],"domain_scores_gemma":[0.9919692,0.001547167,0.002682333,0.000800843,0.00093433,0.002066101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009480943,0.0007787549,0.05806554,0.0006686692,0.0006302332,0.0001222424,0.001987654,0.0009695586,0.9161914,0.0001586783,0.006222289,0.01325686],"study_design_scores_gemma":[0.005600289,0.00161897,0.03418282,0.001974086,0.0009765873,0.001413209,0.004465675,0.0004013054,0.9212574,0.0009815276,0.0250786,0.002049535],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874508,0.006929443,0.00002293088,0.00157373,0.0002902666,0.0008050195,0.00127179,0.00002982475,0.001626176],"genre_scores_gemma":[0.9973575,0.0003711302,0.0006697069,0.0003017572,0.0004301878,0.00005670055,0.00003625974,0.00003716151,0.0007395354],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02388272,"threshold_uncertainty_score":0.9996994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008590246138470235,"score_gpt":0.1797271685618475,"score_spread":0.1711369224233772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}