{"id":"W4214636979","doi":"10.1139/cjc-2021-0320","title":"A new synthesis of (<i>Z</i>,<i>Z</i>)-11,11-dimethoxy-6,9-heneicosadiene and 2-((<i>Z</i>,<i>Z</i>)-1,4-decadienyl)-2-<i><sup>n</sup></i>decyl-1,3-dioxolane, precursors of (<i>Z</i>,<i>Z</i>)-6,9-heneicosadien-11-one, a pheromone component of the whitemarked tussock moth, <i>Orgyia leucostigma</i> (J.E. Smith) (Lepidoptera: Erebidae)","year":2022,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Insect Pheromone Research and Control","field":"Agricultural and Biological Sciences","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Resources Canada; Canadian Forest Service; University of New Brunswick","funders":"Natural Resources Canada; Atlantic Canada Opportunities Agency; Government of Canada","keywords":"Chemistry; Sex pheromone; Stereochemistry; Diene; Bromide; Alkyne; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001258636,0.0006941378,0.0003718246,0.0003852438,0.0003278302,0.000305655,0.0006405514,0.0004379291,0.004495383],"category_scores_gemma":[0.0001235299,0.0002777567,0.0004426968,0.0003211618,0.0002042577,0.0006667382,0.0006635971,0.0009038274,0.0022869],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003136586,"about_ca_system_score_gemma":0.0007002011,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007227978,"about_ca_topic_score_gemma":0.001277789,"domain_scores_codex":[0.9998783,0.000011312,0.00001063001,0.00003475047,0.00002356482,0.00004148205],"domain_scores_gemma":[0.9999113,0.000006661832,0.00001647907,0.00001092039,0.0000169314,0.00003773634],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001776603,0.0002649777,0.0002441739,0.0008765837,0.00004169693,0.000774756,0.0002101489,0.0008430747,0.9381149,0.002319175,0.001031693,0.05510104],"study_design_scores_gemma":[0.0001315843,0.002994793,0.001568763,0.00005483067,0.00007722349,0.001605611,0.0001115793,0.0008283192,0.9136247,0.000836562,0.07808716,0.00007898019],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6390188,0.02614483,0.2143087,0.0008891661,0.00146382,0.002080544,0.004054497,0.00267852,0.1093612],"genre_scores_gemma":[0.8648502,0.01819631,0.08083492,0.0004421068,0.0001136022,0.0009077664,0.002534878,0.0001957296,0.03192431],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004495383,"threshold_uncertainty_score":0.01503855,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008590246138470235,"score_gpt":0.1797271685618475,"score_spread":0.1711369224233772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}