{"id":"W4214696806","doi":"10.1002/marc.202200022","title":"High Refractive Index, Enantiopure Silicones Based on BINOL","year":2022,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrosilylation; Materials science; Refractive index; Elastomer; Silicone; Polymer; Molar mass; High-refractive-index polymer; Copolymer; Polymer chemistry; Enantiopure drug; Chemical engineering; Polymer science; Composite material; Organic chemistry; Chemistry; Catalysis; Enantioselective synthesis; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004503418,0.0002762313,0.0002874279,0.0001039547,0.0009444911,0.00005197443,0.002225034,0.0001181427,0.009830277],"category_scores_gemma":[0.0003900207,0.0003209349,0.0001942024,0.0004877642,0.0002064818,0.00003932188,0.001050543,0.0009978055,0.00004830449],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003151329,"about_ca_system_score_gemma":0.0001762111,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001052012,"about_ca_topic_score_gemma":0.000003056315,"domain_scores_codex":[0.9978458,0.0004556435,0.0003819097,0.0004712357,0.0005077868,0.0003376161],"domain_scores_gemma":[0.9938752,0.0007156428,0.0002457728,0.004990339,0.00007881624,0.00009419706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007790227,0.001006065,0.0001853943,0.00003843668,0.0001280619,0.00003543433,0.0002560766,0.0005307588,0.9735209,0.001450827,0.0005500545,0.02222005],"study_design_scores_gemma":[0.001142078,0.0000533791,0.0001169122,0.00004014832,0.0000801851,0.00006640451,0.0006879217,0.006462378,0.8466066,0.0008138828,0.1434344,0.0004957069],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6264992,0.005171541,0.01389972,0.04506113,0.0009328085,0.001355332,0.001839143,0.002439422,0.3028017],"genre_scores_gemma":[0.9913567,0.00004409084,0.006382789,0.0006303106,0.00003159863,0.0004242455,0.0003332748,0.00008247027,0.0007145093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3648575,"threshold_uncertainty_score":0.9999242,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01730221228082876,"score_gpt":0.2707366347377695,"score_spread":0.2534344224569407,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}