{"id":"W4220687479","doi":"10.1021/acs.inorgchem.1c03817","title":"Thermal Stability and Decomposition Pathways in Volatile Molybdenum(VI) Bis-imides","year":2022,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"MXene and MAX Phase Materials","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Thermogravimetric analysis; Molybdenum; Adduct; Thermal decomposition; Alkyl; Chemical vapor deposition; Thermal stability; Differential scanning calorimetry; Decomposition; Volatility (finance); Inorganic chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004330261,0.0001259851,0.0001801513,0.0000174044,0.0001532282,0.00006130703,0.0001902143,0.00004891775,0.01698709],"category_scores_gemma":[0.00003581814,0.0001322637,0.00002366673,0.0001028558,0.00005459993,0.0001068956,0.0003156642,0.0001151235,0.00001397225],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001228944,"about_ca_system_score_gemma":0.00009981298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001277282,"about_ca_topic_score_gemma":0.000008576967,"domain_scores_codex":[0.9989164,0.00007739326,0.0002680948,0.0003269095,0.0001864983,0.0002246599],"domain_scores_gemma":[0.9995145,0.00004863605,0.00008503523,0.000269878,0.00001898392,0.00006295952],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004468393,0.00009250078,0.0008135056,0.00006377336,0.00000192155,0.00001627903,0.0003295215,0.00001440348,0.9984055,0.00001576894,0.00009844613,0.0001037057],"study_design_scores_gemma":[0.0003945675,0.00002145932,0.00141804,0.000007154803,0.000005863066,0.00002515639,0.0002532786,0.00003899348,0.9971567,0.000267782,0.0002624434,0.0001486055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981222,0.000142849,0.000006192682,0.00007463259,0.0001322486,0.0001144543,0.0001366361,0.00006973574,0.001201039],"genre_scores_gemma":[0.9996359,0.000004495932,0.00005616836,0.00009142861,0.00006951302,0.00004697623,0.0000365564,0.00001508685,0.00004384745],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01697312,"threshold_uncertainty_score":0.9839115,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0152165814090579,"score_gpt":0.2332607842600712,"score_spread":0.2180442028510133,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}