{"id":"W4220760235","doi":"10.1039/d1cp05885a","title":"Time-resolved photoelectron spectroscopy: the continuing evolution of a mature technique","year":2022,"lang":"en","type":"review","venue":"Physical Chemistry Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Ottawa","funders":"","keywords":"Femtosecond; Prospectus; X-ray photoelectron spectroscopy; Excited state; Spectroscopy; Electronic structure; Photoemission spectroscopy; Atomic physics; Chemistry; Ab initio; Physics; Optics; Laser; Nuclear magnetic resonance; Computational chemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":[],"category_scores_codex":[0.000119825,0.001178496,0.002842215,0.00002166861,0.0001710127,0.00003767679,0.001420823,0.0002175219,0.0003220028],"category_scores_gemma":[0.00004349728,0.0009212408,0.001938902,0.0009631955,0.0007220449,0.0001261493,0.0009748465,0.00283946,0.00003826985],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006527801,"about_ca_system_score_gemma":0.0002219388,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001448694,"about_ca_topic_score_gemma":1.496348e-8,"domain_scores_codex":[0.9963086,0.00009940658,0.0008610692,0.001074859,0.0007470215,0.000909043],"domain_scores_gemma":[0.9964688,0.0008463414,0.001160068,0.001251283,0.000113505,0.0001599863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005063929,0.001538827,6.753897e-7,0.007686432,0.001136076,0.000002441932,0.00026231,0.00004536881,0.8630345,0.002032696,0.001616452,0.1225936],"study_design_scores_gemma":[0.0003086414,0.0000343875,1.835695e-8,0.001665131,0.001422824,0.000003303377,0.00007303655,0.0001048613,0.6061639,0.07825448,0.3107891,0.001180239],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00101095,0.9606819,0.005963712,0.00003706729,0.0001268125,0.003574395,0.001665413,0.0004717544,0.02646801],"genre_scores_gemma":[0.2021532,0.7202661,0.003088046,0.00008530646,0.03624779,0.01914875,0.01229191,0.003076771,0.003642132],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.3091727,"threshold_uncertainty_score":0.9994611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009994360258353775,"score_gpt":0.2739126814889159,"score_spread":0.2639183212305621,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}