{"id":"W4220817807","doi":"10.1021/acsnano.2c00831","title":"Tandem Desulfurization/C–C Coupling Reaction of Tetrathienylbenzenes on Cu(111): Synthesis of Pentacene and an Exotic Ladder Polymer","year":2022,"lang":"en","type":"article","venue":"ACS Nano","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Jilin Normal University; Collaborative Innovation Center of Suzhou Nano Science and Technology; Ministry of Science and Technology of the People's Republic of China; National Natural Science Foundation of China; Canada Research Chairs","keywords":"Pentacene; Tandem; Flue-gas desulfurization; Materials science; Polymer; Coupling reaction; Coupling (piping); Nanotechnology; Chemical engineering; Photochemistry; Chemistry; Organic chemistry; Catalysis; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001141683,0.00008571279,0.0001428603,0.00006416093,0.00007155796,0.000006269599,0.00007672998,0.00003796811,0.0000828941],"category_scores_gemma":[0.00002835993,0.00009363228,0.00002908199,0.0002413618,0.00002023529,0.00008866228,0.00002194535,0.0000660998,8.740053e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002913741,"about_ca_system_score_gemma":0.00001023747,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001579594,"about_ca_topic_score_gemma":0.000002873714,"domain_scores_codex":[0.9994553,0.00001164501,0.0001652458,0.0001227985,0.0001525391,0.00009252006],"domain_scores_gemma":[0.9996209,0.00009608478,0.00005258012,0.0001777204,0.00002187688,0.00003089961],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001543041,0.00004752547,0.002023942,0.00004916036,0.00004451453,0.000001474773,0.0001315196,0.01348839,0.9832806,0.00001832892,0.00001957113,0.0008795361],"study_design_scores_gemma":[0.0001128104,0.00003224174,0.001342791,0.00001729872,0.00005644708,0.000005948776,0.0006333439,0.001966965,0.9957024,0.000008463166,0.00002825863,0.00009302532],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989325,0.0004692147,0.00004527643,0.000009652451,0.00007061286,0.0000400568,0.00001844443,0.00004508979,0.0003691656],"genre_scores_gemma":[0.9997269,0.0000934269,0.00003609911,0.000005650207,0.00001900977,0.00001328239,0.00002317735,0.00001825111,0.00006423004],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0124218,"threshold_uncertainty_score":0.3818214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01357315236295898,"score_gpt":0.211800627807495,"score_spread":0.1982274754445361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}