{"id":"W4220954759","doi":"10.1021/jacs.1c13028","title":"Taming Tris(bipyridine)ruthenium(II) and Its Reactions in Water by Capture/Release with Shape-Switchable Symmetry-Matched Cyclophanes","year":2022,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"China Scholarship Council; Queen's University; Queen's University Belfast; Leverhulme Trust; Department of Education and Learning, Northern Ireland","keywords":"Chemistry; Ruthenium; Excited state; Bipyridine; Tris; Photochemistry; Symmetry (geometry); Molecule; Chemical physics; Luminescence; Proton; Combinatorial chemistry; Crystallography; Catalysis; Atomic physics; Crystal structure; Organic chemistry; Optoelectronics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002149829,0.0001617741,0.0003264307,0.00002514767,0.0002738631,0.00002577664,0.0002332782,0.00004997509,0.0002085874],"category_scores_gemma":[0.00004254384,0.00009971509,0.0002384596,0.0003052785,0.0000993588,0.00007679011,0.0001788459,0.0008635577,5.746311e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002372656,"about_ca_system_score_gemma":0.0000345218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001859723,"about_ca_topic_score_gemma":8.538858e-7,"domain_scores_codex":[0.9987455,0.00004541558,0.0003467165,0.0001918267,0.0004090398,0.0002615275],"domain_scores_gemma":[0.9991791,0.0000597714,0.0004389712,0.0001563821,0.00005934383,0.000106486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001559423,0.0001179376,0.000263512,0.00002535655,0.00007619395,0.000006866432,0.0008164439,0.0001228685,0.9963987,0.000001292516,0.001535357,0.0004795139],"study_design_scores_gemma":[0.000895302,0.00008721994,0.00003186001,0.0000330046,0.0000722647,0.0003683787,0.004310062,0.002764484,0.9807236,0.00003369193,0.01048773,0.0001924181],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977224,0.0003010225,0.00001960387,0.001717081,0.00004842451,0.00004681978,0.00001019512,0.00001381107,0.0001206094],"genre_scores_gemma":[0.998498,0.0001089513,0.0001687668,0.0004418779,0.00009449957,0.000009482288,0.000003582105,0.00002705524,0.0006478287],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01567513,"threshold_uncertainty_score":0.4066264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005232118860746092,"score_gpt":0.2010362066105331,"score_spread":0.195804087749787,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}