{"id":"W4220969860","doi":"10.1021/acs.biomac.1c01591","title":"Competing Effects of Hydration and Cation Complexation in Single-Chain Alginate","year":2022,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canada Excellence Research Chairs, Government of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Polyelectrolyte; Hydrogen bond; Intramolecular force; Alginic acid; Counterion; Aqueous solution; Intermolecular force; Calcium alginate; Side chain; Polymer chemistry; Crystallography; Stereochemistry; Molecule; Polymer; Ion; Organic chemistry; Calcium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001985056,0.00009626622,0.0001080953,0.00009145397,0.0001166181,0.0000122523,0.000103449,0.00004257093,0.000005191464],"category_scores_gemma":[0.00009247205,0.0001087022,0.00002746986,0.0001484114,0.00007235552,0.000004336455,0.0001279029,0.00004173424,0.000001168372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003427337,"about_ca_system_score_gemma":0.00002558559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001379636,"about_ca_topic_score_gemma":0.00004788734,"domain_scores_codex":[0.9991278,0.000170384,0.0002150678,0.0002475374,0.0001149112,0.0001242864],"domain_scores_gemma":[0.9995949,0.00002575966,0.0001346503,0.0001842289,0.00003405224,0.00002641544],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002131914,0.0001055678,0.001024038,0.00004670548,0.00001139425,0.000001336403,0.0002415503,0.0000926054,0.9931507,0.0002475196,0.00001574976,0.005041567],"study_design_scores_gemma":[0.0003616465,0.0001877709,0.007438118,0.00001592215,0.00001017954,0.00001269377,0.0001529725,0.001218619,0.9890744,0.0001401397,0.001257533,0.0001299691],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954667,0.0008835644,0.002887634,0.0001710117,0.00003220984,0.0003252569,0.00001388002,0.00001262988,0.0002070751],"genre_scores_gemma":[0.9985948,0.00001635208,0.0009371876,0.0000575903,0.00001954025,0.0001433647,0.0001934379,0.00001685007,0.00002086094],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006414081,"threshold_uncertainty_score":0.4432746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01208924229349951,"score_gpt":0.2258765744747463,"score_spread":0.2137873321812468,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}