{"id":"W4221016225","doi":"10.1039/d2cc00543c","title":"Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide","year":2022,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Julius-Maximilians-Universität Würzburg; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior; Deutsche Forschungsgemeinschaft; Alexander von Humboldt-Stiftung","keywords":"Synthon; Chemistry; Azide; Adduct; Lewis acids and bases; Ring (chemistry); Yield (engineering); Computational chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Materials science; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001212201,0.0002866335,0.0002511035,0.0001253239,0.0002090046,0.0003537688,0.0002879737,0.0003377305,0.001807799],"category_scores_gemma":[0.000121199,0.0001674414,0.0001140726,0.00009941905,0.0002632448,0.0003065583,0.0003402018,0.0004541607,0.0004806847],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001722408,"about_ca_system_score_gemma":0.0001156904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003257736,"about_ca_topic_score_gemma":0.0005053491,"domain_scores_codex":[0.9999003,0.00001339845,0.000004812643,0.00003008659,0.0000190259,0.00003231184],"domain_scores_gemma":[0.9999615,0.000006085231,0.00001052496,0.000005075767,0.000005635578,0.00001124458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001788256,0.00001745199,0.0001819399,0.00008003375,0.000009069121,0.0001263372,0.00006337111,0.0001674569,0.9970058,0.0008524641,0.0001301062,0.001187193],"study_design_scores_gemma":[0.00002552718,0.0002756178,0.0003165267,0.000006721825,0.000007773917,0.0001495146,0.00003605083,0.0004925946,0.9955561,0.0001375423,0.00298737,0.000008603432],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923849,0.001095592,0.003184215,0.0001041412,0.00003174333,0.00002464739,0.0001708005,0.000102381,0.002901612],"genre_scores_gemma":[0.9960694,0.0004714481,0.001294133,0.0000339377,0.000008056308,0.00001706401,0.0001556706,0.00002371886,0.001926477],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001807799,"threshold_uncertainty_score":0.006047726,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01411415602684729,"score_gpt":0.2501648170927758,"score_spread":0.2360506610659285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}