{"id":"W4221057132","doi":"10.1002/chem.202200666","title":"The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6‐<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>N)}<sub>2</sub>)GePCO","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Science Foundation of Ningbo; Natural Science Foundation of Ningbo Municipality; Deutsche Forschungsgemeinschaft","keywords":"Alkyne; Nucleophile; Reactivity (psychology); Frustrated Lewis pair; Chemistry; Intramolecular force; Electrophile; Lewis acids and bases; Intermolecular force; Medicinal chemistry; Stereochemistry; Electron pair; Electron; Catalysis; Molecule; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004644804,0.0001872444,0.0001442837,0.00007960147,0.000174708,0.0002927738,0.0001932679,0.00022976,0.004770855],"category_scores_gemma":[0.0001018029,0.00007675843,0.00006606405,0.00006140616,0.0001737481,0.0002324414,0.0002070926,0.0002229191,0.0002522889],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001527699,"about_ca_system_score_gemma":0.0001093528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003089236,"about_ca_topic_score_gemma":0.0005364873,"domain_scores_codex":[0.9999748,0.00000257532,5.765061e-7,0.000004918063,0.000004988723,0.00001200525],"domain_scores_gemma":[0.9999783,0.000008077748,0.000003700376,0.000002455639,0.000002330873,0.000005079804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008696195,0.0001202486,0.002496422,0.0006894523,0.00006981997,0.001020875,0.0002539232,0.02042113,0.9334645,0.02556524,0.001883806,0.01314498],"study_design_scores_gemma":[0.0001770045,0.001502539,0.009055071,0.00004840441,0.00009258575,0.0007144896,0.0005179054,0.1113714,0.8596626,0.00660724,0.01018829,0.00006262265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957699,0.0001334742,0.0004596962,0.00003750668,0.00001162446,0.000003650988,0.00005389704,0.00001944853,0.003510733],"genre_scores_gemma":[0.999316,0.00007426178,0.00009505067,0.000005372512,0.000001289109,0.000002977508,0.00004013725,0.000004874958,0.0004600808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004770855,"threshold_uncertainty_score":0.01596004,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01011119020738599,"score_gpt":0.1930472405547176,"score_spread":0.1829360503473316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}