{"id":"W4221131239","doi":"10.1039/d2ob00131d","title":"ROESY and <sup>13</sup>C NMR to distinguish between <scp>d</scp>- and <scp>l</scp>-rhamnose in the α-<scp>d</scp>-Man<i>p</i>-(1 → 4)-β-Rha<i>p</i>-(1 → 3) repeating motif","year":2022,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo; University of Guelph","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Rhamnose; Chemistry; Disaccharide; Stereochemistry; Mannose; Residue (chemistry); Polysaccharide; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003827928,0.0008089996,0.0003032202,0.0007182426,0.0004962733,0.0004991039,0.000630921,0.0008017424,0.014124],"category_scores_gemma":[0.000954527,0.000262905,0.0002578453,0.001180365,0.0008643104,0.0007687206,0.0003449933,0.001723278,0.003058987],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003717563,"about_ca_system_score_gemma":0.0006636869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002536554,"about_ca_topic_score_gemma":0.004756163,"domain_scores_codex":[0.9997221,0.00003116958,0.00001403676,0.00006733767,0.00006054859,0.0001048638],"domain_scores_gemma":[0.9992411,0.0002052514,0.000129925,0.0001137188,0.0002107367,0.00009920966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004984973,0.00006492202,0.0004885067,0.0001383363,0.00003322551,0.0004461586,0.0001139687,0.0004303765,0.9867333,0.0005892611,0.001386005,0.009077555],"study_design_scores_gemma":[0.00004266058,0.0003756264,0.008309403,0.00002764814,0.00007803527,0.00109281,0.0002972016,0.003244699,0.9579685,0.0008929659,0.0276055,0.00006499108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8488427,0.006682136,0.05225081,0.00234351,0.00105476,0.0001826037,0.006297003,0.001291835,0.08105457],"genre_scores_gemma":[0.9110605,0.00302027,0.04173765,0.001574165,0.0001660455,0.000244092,0.008855887,0.0006447881,0.03269652],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.014124,"threshold_uncertainty_score":0.0472495,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008642470020104133,"score_gpt":0.2109821047883229,"score_spread":0.2023396347682187,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}