{"id":"W4223950644","doi":"10.1021/acs.organomet.1c00661","title":"Oxalamide-Bridged Ferrocenes: Conformational and Gelation Properties and <i>In Vitro</i> Antitumor Activity","year":2022,"lang":"en","type":"article","venue":"Organometallics","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"The Scarborough Hospital; University of Toronto","funders":"Hrvatska Zaklada za Znanost","keywords":"Chemistry; HeLa; Intramolecular force; Conformational isomerism; Hydrogen bond; Supramolecular chemistry; Stereochemistry; Toluene; Ferrocene; In vitro; Crystallography; Crystal structure; Molecule; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001022916,0.0001238042,0.0001433994,0.00003907605,0.0002845913,0.00004485547,0.00009606522,0.00004121386,0.0002928797],"category_scores_gemma":[0.00002987311,0.0001314993,0.0000208428,0.0001662415,0.00007813047,0.0002051219,0.0001478969,0.0002099039,0.000003122042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007218243,"about_ca_system_score_gemma":0.00005649127,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001263221,"about_ca_topic_score_gemma":0.000002517952,"domain_scores_codex":[0.9992821,0.00001049331,0.0001726821,0.0002209217,0.0001635443,0.0001503257],"domain_scores_gemma":[0.9996621,0.00003088392,0.00008253866,0.0001443441,0.00002510148,0.00005504464],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006525215,0.00007970316,0.001807841,0.0001293047,0.00001040292,0.00000140482,0.0001992546,0.00006351231,0.9965003,0.0001829302,0.00002557597,0.0009344804],"study_design_scores_gemma":[0.0005118187,0.000005861692,0.006645894,0.000008041772,0.00001593016,0.00005929023,0.0004448229,0.002496477,0.9847708,0.0001462267,0.004684153,0.0002107284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966217,0.0002331283,0.00002933638,0.000413155,0.00001316693,0.00007419934,0.000075301,0.00004619366,0.002493829],"genre_scores_gemma":[0.9986055,0.00005912453,0.00008992082,0.00006998282,0.0000293351,0.00008085091,0.0001233876,0.00001428821,0.000927577],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01172958,"threshold_uncertainty_score":0.5362387,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02209557759098399,"score_gpt":0.2038260362981602,"score_spread":0.1817304587071762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}