{"id":"W4224213620","doi":"10.1021/acs.inorgchem.2c00279","title":"Deciphering Distinct Overpotential-Dependent Pathways for Electrochemical CO <sub>2</sub> Reduction Catalyzed by an Iron–Terpyridine Complex","year":2022,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Basic Energy Sciences; Office of Science; Lawrence Berkeley National Laboratory; Canadian Institute for Advanced Research; Chevron; U.S. Department of Energy","keywords":"Overpotential; Chemistry; Electron transfer; Electrochemistry; Electrocatalyst; Catalysis; Electrochemical potential; Chemical physics; Photochemistry; Physical chemistry; Electrode; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000217846,0.00031636,0.0002486534,0.0001291222,0.0001700541,0.0005505898,0.0005877651,0.0004225103,0.0007828142],"category_scores_gemma":[0.0005659733,0.0002762804,0.0001918922,0.0001087253,0.0002578483,0.0006986714,0.0001742302,0.0005625576,0.0001369884],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004930947,"about_ca_system_score_gemma":0.0004566087,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009341568,"about_ca_topic_score_gemma":0.001357848,"domain_scores_codex":[0.9999413,0.000007276318,0.000003577885,0.00001401998,0.00002016229,0.00001364868],"domain_scores_gemma":[0.9998668,0.00007096766,0.00002721645,0.0000128738,0.00001566078,0.000006459833],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008350773,0.0004930327,0.009240649,0.001049576,0.00009569019,0.0007380039,0.0002558549,0.1495913,0.7464653,0.04179304,0.0008385704,0.04860404],"study_design_scores_gemma":[0.00005828213,0.0001728709,0.002972305,0.00001205192,0.00002781738,0.0001233163,0.00009141092,0.7692986,0.222238,0.003830449,0.001152856,0.0000220938],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858308,0.0002092554,0.01156203,0.000123542,0.00001051058,0.00002341868,0.00009063796,0.0001259109,0.002023842],"genre_scores_gemma":[0.9959351,0.000156237,0.003621619,0.00001574482,0.000002428923,0.00001924472,0.0000853314,0.00001173674,0.0001525622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009341568,"threshold_uncertainty_score":0.00357765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01099756104925048,"score_gpt":0.2272555389980836,"score_spread":0.2162579779488331,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}