{"id":"W4224847246","doi":"10.1002/anie.202204851","title":"(PNSiMe <sub>3</sub> ) <sub>4</sub> (NMe) <sub>6</sub> : A Robust Tetravalent Phosphaza‐adamantane Scaffold for Molecular and Macromolecular Construction**","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Adamantane; Covalent bond; Macromolecule; Chemistry; Thermal stability; Iminium; Scaffold; Surface modification; Polymer chemistry; Combinatorial chemistry; Ion; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008218363,0.0001795266,0.0001213304,0.0000815201,0.0001132192,0.0002020369,0.0001927361,0.0001673921,0.001577896],"category_scores_gemma":[0.00007939187,0.0000869119,0.0000917346,0.00007577386,0.0001571144,0.0002344483,0.0002276633,0.0002006629,0.0005016582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001024148,"about_ca_system_score_gemma":0.00007965857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008694515,"about_ca_topic_score_gemma":0.0001583476,"domain_scores_codex":[0.9999645,0.000005731847,0.000002642968,0.00001002544,0.000008847392,0.000008300418],"domain_scores_gemma":[0.9999586,0.000006429964,0.00001324925,0.000006462608,0.000005521639,0.000009746203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000680304,0.00001161755,0.00009202388,0.00005755705,0.000003846844,0.00009025932,0.00001570324,0.0002539086,0.9939459,0.00108027,0.000146356,0.004234648],"study_design_scores_gemma":[0.000008710772,0.0001569544,0.0003020192,0.000002178904,0.000004150887,0.0001944331,0.000008916016,0.001037508,0.9928573,0.0001915731,0.0052318,0.000004450148],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9718961,0.0007229894,0.02011118,0.0001554813,0.00007745704,0.00002990852,0.0002314629,0.0004408462,0.006334596],"genre_scores_gemma":[0.9832969,0.0003048902,0.01287506,0.00003679683,0.00001118078,0.00002686648,0.0001443822,0.00004235903,0.003261607],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001577896,"threshold_uncertainty_score":0.005278528,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009642124689296143,"score_gpt":0.2117447424862262,"score_spread":0.20210261779693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}