{"id":"W4224847246","doi":"10.1002/anie.202204851","title":"(PNSiMe <sub>3</sub> ) <sub>4</sub> (NMe) <sub>6</sub> : A Robust Tetravalent Phosphaza‐adamantane Scaffold for Molecular and Macromolecular Construction**","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Adamantane; Covalent bond; Macromolecule; Chemistry; Thermal stability; Iminium; Scaffold; Surface modification; Polymer chemistry; Combinatorial chemistry; Ion; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003254153,0.0007070083,0.0005302618,0.0001876205,0.0005977705,0.0002413528,0.0006333233,0.0003337078,0.0003495948],"category_scores_gemma":[0.0002252957,0.0008858368,0.0004851099,0.0003283698,0.0003401444,0.0003700483,0.0004563213,0.0006679253,0.0000211342],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006059126,"about_ca_system_score_gemma":0.0002003911,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001435199,"about_ca_topic_score_gemma":0.000007610994,"domain_scores_codex":[0.9957805,0.00005364254,0.0008159197,0.001282771,0.001326916,0.0007402623],"domain_scores_gemma":[0.997905,0.0002019869,0.0005070591,0.0005986759,0.0004596086,0.0003276333],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003515742,0.0003496882,0.0001204917,0.0002607837,0.0005413152,0.0003238649,0.0001121019,0.0003918484,0.987806,0.0003974228,0.004808975,0.004535985],"study_design_scores_gemma":[0.002493171,0.00009892821,0.00004941247,0.0001726614,0.0002790829,0.001097155,0.0004423374,0.0007891867,0.9877582,0.001993543,0.003919132,0.0009072426],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9856891,0.0009024945,0.007443231,0.0007535894,0.001200662,0.0004134243,0.00153397,0.0002737695,0.001789757],"genre_scores_gemma":[0.9915484,0.0003147298,0.0005247623,0.0006402832,0.001301888,0.0007261827,0.004746208,0.0001450018,0.00005255134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006918469,"threshold_uncertainty_score":0.9993593,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009642124689296143,"score_gpt":0.2117447424862262,"score_spread":0.20210261779693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}