{"id":"W4225378799","doi":"10.1016/j.apcatb.2022.121451","title":"Molecular engineering to introduce carbonyl between nickel salophen active sites to enhance electrochemical CO2 reduction to methanol","year":2022,"lang":"en","type":"article","venue":"Applied Catalysis B: Environmental","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Western University","funders":"Canadian Institutes of Health Research; Universitat Autònoma de Barcelona; High Energy Accelerator Research Organization; Generalitat de Catalunya; Ministerio de Ciencia e Innovación; Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España; Institució Catalana de Recerca i Estudis Avançats; Agencia Estatal de Investigación; China Postdoctoral Science Foundation; European Regional Development Fund; European Commission; China Scholarship Council; Institut Català de Nanociència i Nanotecnologia; Centres de Recerca de Catalunya; Ministerio de Ciencia, Innovación y Universidades; University of Saskatchewan; Natural Sciences and Engineering Research Council of Canada; Canadian Light Source","keywords":"Nickel; Methanol; Electrochemistry; Reduction (mathematics); Chemistry; Combinatorial chemistry; Organic chemistry; Electrode; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006459935,0.0003226733,0.0001117042,0.0001151631,0.00009874898,0.0002115852,0.0002988649,0.0002134388,0.001178725],"category_scores_gemma":[0.0001160502,0.0001380219,0.0001713422,0.0001154221,0.0001531784,0.0001999818,0.0002121929,0.0002749895,0.0003014222],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000269352,"about_ca_system_score_gemma":0.0001704612,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004365064,"about_ca_topic_score_gemma":0.0009381808,"domain_scores_codex":[0.9999495,0.000006794391,0.000002961989,0.000008713877,0.00001483214,0.00001722107],"domain_scores_gemma":[0.9999561,0.000007007748,0.00001225561,0.000006097107,0.000006475708,0.00001199365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004406148,0.0000394444,0.0001556381,0.00008078806,0.000008797483,0.0001146524,0.00001592663,0.0004223664,0.9959901,0.0007012545,0.00006266247,0.002364355],"study_design_scores_gemma":[0.00001919769,0.0001343521,0.0006136179,0.00000386408,0.00001199629,0.0001037178,0.00001539534,0.002168314,0.9933258,0.00007422168,0.003521179,0.000008325211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832856,0.0005814206,0.01186518,0.00013853,0.00005964143,0.00005881598,0.0001305415,0.0001783127,0.003701982],"genre_scores_gemma":[0.988677,0.0004133067,0.00853232,0.0000403859,0.000006712904,0.00003747769,0.00009351753,0.00001638943,0.002183035],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001178725,"threshold_uncertainty_score":0.003943205,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003499449660846296,"score_gpt":0.2099736868267204,"score_spread":0.2064742371658741,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}