{"id":"W4225402036","doi":"10.1096/fasebj.2022.36.s1.r2723","title":"Transformations of phosphonates by non‐heme iron‐dependent oxygenases","year":2022,"lang":"en","type":"article","venue":"The FASEB Journal","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Cleave; Chemistry; Oxygenase; Heme; Limiting; Enzyme; Biochemistry; Catabolism; Stereochemistry; Molecule; Dioxygenase; Bond cleavage; Small molecule; Heme oxygenase; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001529185,0.0004888412,0.0001365737,0.0001186155,0.000135214,0.0002696172,0.0002897451,0.0003358043,0.001470749],"category_scores_gemma":[0.0002254505,0.0001727212,0.0002709533,0.0001094508,0.000177335,0.0006218226,0.0003610594,0.0005437785,0.0007121551],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002843512,"about_ca_system_score_gemma":0.0002655633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004796599,"about_ca_topic_score_gemma":0.0009012488,"domain_scores_codex":[0.9998699,0.00001751842,0.000008034205,0.00003214041,0.00003673183,0.00003563303],"domain_scores_gemma":[0.9999672,0.000007075167,0.000006714008,0.000005597467,0.000006750064,0.000006672263],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001400531,0.00006454685,0.0001992139,0.0003117006,0.00001726141,0.0003938781,0.0001164751,0.0006871315,0.9722642,0.00547757,0.0005390863,0.01978894],"study_design_scores_gemma":[0.00001279677,0.0001078265,0.0001987923,0.00001133803,0.000006091922,0.0002510673,0.00003064659,0.0008029816,0.9832372,0.0006454301,0.01468708,0.000008784079],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8647588,0.01960548,0.06746142,0.000838118,0.0007878543,0.0002130531,0.0007744257,0.0004683871,0.04509242],"genre_scores_gemma":[0.9626438,0.009586776,0.01406006,0.0001601313,0.00004870013,0.00005689638,0.0004306997,0.00008169235,0.01293132],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001470749,"threshold_uncertainty_score":0.004920125,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140280216157323,"score_gpt":0.243110541603462,"score_spread":0.2317077394418888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}