{"id":"W4225428966","doi":"10.1021/acs.langmuir.0c03358","title":"Comparative Thermodynamic Studies of the Micellization of Amphiphilic Block Copolymers before and after Cyclization","year":2022,"lang":"en","type":"article","venue":"Langmuir","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Japan Society for the Promotion of Science; Asahi Glass Foundation","keywords":"Copolymer; Micelle; Polymer chemistry; Amphiphile; Acrylate; Ethylene oxide; Isothermal titration calorimetry; Ethyl acrylate; Critical micelle concentration; Materials science; Enthalpy; Chemistry; Thermodynamics; Organic chemistry; Aqueous solution; Physical chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004450373,0.00006239166,0.0001535885,0.00001558289,0.00008383911,0.000003045794,0.00007865105,0.00001917905,0.000104399],"category_scores_gemma":[0.000004440588,0.00004326602,0.00003226328,0.0001235766,0.00007371861,0.00001891102,0.00007515832,0.00004329937,2.701432e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002795611,"about_ca_system_score_gemma":0.00000940973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006021199,"about_ca_topic_score_gemma":0.0001293235,"domain_scores_codex":[0.9995222,0.00003436493,0.0001494933,0.00008870097,0.0001450233,0.00006020053],"domain_scores_gemma":[0.9996853,0.00002672517,0.00014065,0.0001058765,0.00003293238,0.000008550414],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001995886,0.0001716265,0.4063239,0.0006386193,0.0004269276,0.000001838481,0.04475449,0.0006515489,0.544843,0.001071821,0.0001899666,0.0007267352],"study_design_scores_gemma":[0.003346312,0.0002828212,0.5026263,0.0004722098,0.0004635058,0.00004073509,0.110807,0.01440395,0.3600686,0.001925716,0.004703455,0.0008594462],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973485,0.001108518,0.00000185827,0.00004733379,0.00005445735,0.00007250696,0.00006471385,0.000009081689,0.001292978],"genre_scores_gemma":[0.9992989,0.0000107384,0.000002034667,0.00001643505,0.00001479955,0.00002540185,0.000008376517,0.000006579939,0.000616676],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1847744,"threshold_uncertainty_score":0.1764337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01400188962214209,"score_gpt":0.2504793068734305,"score_spread":0.2364774172512884,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}