{"id":"W4225479863","doi":"10.1039/d2re00048b","title":"Quantitative and convenient real-time reaction monitoring using stopped-flow benchtop NMR","year":2022,"lang":"en","type":"article","venue":"Reaction Chemistry & Engineering","topic":"NMR spectroscopy and applications","field":"Physics and Astronomy","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; University of British Columbia; Bristol-Myers Squibb","keywords":"Flow (mathematics); Process engineering; Computer science; Chemistry; Materials science; Analytical Chemistry (journal); Chromatography; Engineering; Mechanics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002142668,0.001372622,0.0008905466,0.0006603946,0.0005201946,0.001134329,0.001738841,0.0009990961,0.001628579],"category_scores_gemma":[0.001500692,0.0005807265,0.0004139701,0.0004690834,0.0007986702,0.0009372441,0.0004374005,0.001649937,0.001020071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003636664,"about_ca_system_score_gemma":0.0007018142,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003891363,"about_ca_topic_score_gemma":0.0004810099,"domain_scores_codex":[0.998811,0.0003776862,0.00006236299,0.0002531899,0.0003962164,0.00009951161],"domain_scores_gemma":[0.9988565,0.0005295537,0.0001295165,0.000131797,0.0002610703,0.00009138457],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001193692,0.00006090035,0.00008520712,0.0001012336,0.00001055974,0.0000300195,0.00002099102,0.0001489823,0.9938769,0.0005562466,0.0002506976,0.004738935],"study_design_scores_gemma":[0.0000216805,0.0001976263,0.0001938985,0.000006127747,0.00001489624,0.00006360814,0.000007964863,0.002908848,0.9938623,0.0001342473,0.002564629,0.0000242536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.2069702,0.003876691,0.7769271,0.0005360481,0.0004125931,0.0005457235,0.001523845,0.006611936,0.002595905],"genre_scores_gemma":[0.3459476,0.004101404,0.6407834,0.0003310871,0.0003449263,0.0008782046,0.003029477,0.0004268958,0.004157046],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.002142668,"threshold_uncertainty_score":0.01133162,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01180822060745465,"score_gpt":0.2930676381978836,"score_spread":0.281259417590429,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}