{"id":"W4226301486","doi":"10.1002/ange.202202364","title":"Stereoselective Synthesis of Allenyl Alcohols by Cobalt(III)‐Catalyzed Sequential C−H Bond Addition to 1,3‐Enynes and Aldehydes","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Foundation for the National Institutes of Health","keywords":"Stereoselectivity; Cobalt; Catalysis; Chemistry; Medicinal chemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001618705,0.0006477574,0.0002666344,0.0002804686,0.0001653534,0.0002182044,0.000279686,0.0001882736,0.001597042],"category_scores_gemma":[0.0001287321,0.0001950414,0.0002302901,0.0001905897,0.0001988636,0.0002336287,0.0003529916,0.0004107708,0.000804897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003077836,"about_ca_system_score_gemma":0.0005644872,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001077558,"about_ca_topic_score_gemma":0.003706154,"domain_scores_codex":[0.9998776,0.00001050824,0.000009516048,0.00002200104,0.00002517543,0.00005524217],"domain_scores_gemma":[0.9999356,0.000006045111,0.00001054057,0.00001074354,0.00001346746,0.00002365978],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008805304,0.00005942022,0.0001919601,0.0001688259,0.00002442902,0.000474376,0.0001107005,0.000646717,0.9863243,0.001945281,0.0004464543,0.009519447],"study_design_scores_gemma":[0.00001902417,0.0001634952,0.000373518,0.000005728803,0.00001351562,0.0001543474,0.00002175791,0.0004429425,0.9921475,0.0001389307,0.00650987,0.000009412523],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9265044,0.002888048,0.03856872,0.000271558,0.0003304999,0.0003469853,0.001105601,0.0006234607,0.02936069],"genre_scores_gemma":[0.9829458,0.001536905,0.01069254,0.00004565558,0.00001613709,0.00004893352,0.0002937541,0.00003847083,0.004381663],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001597042,"threshold_uncertainty_score":0.005342662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02149194383187844,"score_gpt":0.2717738584420188,"score_spread":0.2502819146101404,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}