{"id":"W4226467742","doi":"10.1039/d1an02224e","title":"Naphthalene-functionalized resorcinarene as selective, fluorescent self-quenching sensor for kynurenic acid","year":2022,"lang":"en","type":"article","venue":"The Analyst","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund; Oakland University","keywords":"Kynurenic acid; Chemistry; Anthranilic acid; Resorcinarene; Isothermal titration calorimetry; Titration; Tryptophan; Fluorescence; Combinatorial chemistry; Photochemistry; Organic chemistry; Molecule; Biochemistry; Amino acid","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001512752,0.00025982,0.0003872202,0.0001402482,0.001463274,0.0001543873,0.0007055645,0.00005208801,0.004177311],"category_scores_gemma":[0.0001115388,0.0001877992,0.0002347317,0.000397855,0.00008371323,0.0001786115,0.0002848472,0.0001667713,0.0002440957],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002404705,"about_ca_system_score_gemma":0.0001647257,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002168824,"about_ca_topic_score_gemma":0.00001899109,"domain_scores_codex":[0.9973072,0.0004898979,0.0004659874,0.0005489528,0.0006441622,0.0005438074],"domain_scores_gemma":[0.9987107,0.0001580163,0.0002654376,0.000605225,0.0001663788,0.0000942705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005832375,0.0001574726,0.0004715071,0.00003754279,0.00008464626,0.00001382262,0.000666733,0.0002451402,0.9874979,0.001066702,0.009069669,0.0001056283],"study_design_scores_gemma":[0.001903146,0.0005375781,0.001298339,0.0000307401,0.0004265575,0.0002135438,0.00101389,0.0006598034,0.9267646,0.002025804,0.0645237,0.0006023078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949033,0.0004643094,0.0003101907,0.001440577,0.001009507,0.0007877179,0.0001615885,0.0002445369,0.0006783115],"genre_scores_gemma":[0.9951635,0.00002961242,0.001132287,0.0006146843,0.0004890964,0.0006187616,0.0000921803,0.00004214098,0.001817708],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0607333,"threshold_uncertainty_score":0.9998367,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01446617266547017,"score_gpt":0.2574557189353696,"score_spread":0.2429895462698994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}