{"id":"W4229003552","doi":"10.26434/chemrxiv-2022-k2snf","title":"Coupled interfacial and bulk kinetics govern the timescales of multiphase ozonolysis reactions","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Lawrence Berkeley National Laboratory; Chemical Sciences, Geosciences, and Biosciences Division; Natural Sciences and Engineering Research Council of Canada; Basic Energy Sciences; University of Bristol; Royal Holloway, University of London; U.S. Department of Energy","keywords":"Ozonolysis; Aerosol; Chemistry; Diffusion; Particle (ecology); Kinetic energy; Chemical physics; Thermodynamics; Ozone; Reaction rate; Kinetics; Aqueous solution; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005227749,0.0009237244,0.0006047408,0.0003804234,0.0004041184,0.001039154,0.0011895,0.0008602508,0.001499429],"category_scores_gemma":[0.002012255,0.0006208124,0.0009126094,0.00024363,0.000687195,0.002489577,0.0008427656,0.001037321,0.0004664635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001511116,"about_ca_system_score_gemma":0.001118865,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006283072,"about_ca_topic_score_gemma":0.002524441,"domain_scores_codex":[0.999595,0.0000274285,0.00002623573,0.0001505936,0.0001075707,0.0000931492],"domain_scores_gemma":[0.9992521,0.0003346617,0.0001823719,0.00006458243,0.0001126845,0.00005351804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002572766,0.0002907775,0.01253825,0.000603892,0.0001462409,0.0003842399,0.0002722874,0.4525587,0.453356,0.05528624,0.0007671731,0.02353888],"study_design_scores_gemma":[0.00003358594,0.00009059491,0.003251595,0.00001205514,0.00005129553,0.0000798097,0.00004336001,0.9281853,0.05642197,0.009744396,0.002043043,0.00004305222],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7074652,0.002322884,0.2772374,0.000659607,0.0001608663,0.0002211437,0.0007676352,0.0006506289,0.01051465],"genre_scores_gemma":[0.9904962,0.001021569,0.005979029,0.00007030309,0.00002147748,0.0001053589,0.000256681,0.00007541019,0.001974027],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006283072,"threshold_uncertainty_score":0.01249301,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01750003396637612,"score_gpt":0.2289293986093216,"score_spread":0.2114293646429455,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}