{"id":"W4229625143","doi":"10.1002/ange.200701194","title":"The Geometric and Electronic Structure of a One‐Electron‐Oxidized Nickel(II) Bis(salicylidene)diamine Complex","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; National Institutes of Health; U.S. Department of Energy","keywords":"Chemistry; Diamine; Nickel; Polymer chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005706797,0.0003202022,0.0004369381,0.0002128285,0.0003042123,0.00004878722,0.0004798367,0.0002336851,0.0007607979],"category_scores_gemma":[0.0003819163,0.0002600882,0.0001329487,0.0009277578,0.0001584854,0.0001041095,0.0001916043,0.0004069384,0.000005653911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001831754,"about_ca_system_score_gemma":0.000136393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006247066,"about_ca_topic_score_gemma":0.0002179684,"domain_scores_codex":[0.9975717,0.00001917962,0.0005794535,0.0004477724,0.0005595259,0.0008223547],"domain_scores_gemma":[0.9982299,0.0003755828,0.0003777643,0.0006567672,0.000191044,0.0001689065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000886808,0.00005207445,0.00006457505,0.00008811821,0.0001657288,0.000002519685,0.00008508548,8.357893e-7,0.9960288,0.001817371,0.0006504068,0.0009557855],"study_design_scores_gemma":[0.001272708,0.0000582739,0.000250436,0.0000171385,0.00009491467,0.00003505347,0.00009921129,0.000008213329,0.9748196,0.001910396,0.02116352,0.000270552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913332,0.004079781,0.0003005094,0.0002730073,0.00005370227,0.0001662607,0.00007250876,0.00009261612,0.00362837],"genre_scores_gemma":[0.9956953,0.0005865365,0.0006594439,0.0001361072,0.0001900601,0.000009730189,0.000231586,0.00005574241,0.00243552],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02120923,"threshold_uncertainty_score":0.9999852,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01760770070973136,"score_gpt":0.2534714240121841,"score_spread":0.2358637233024527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}