{"id":"W4229864351","doi":"10.1002/ange.201607522","title":"Stereo‐ and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"European Research Council","keywords":"Alkyne; Regioselectivity; Chemistry; Radical; Stereospecificity; Hydride; Radical initiator; Reaction mechanism; Medicinal chemistry; Stereochemistry; Photochemistry; Metal; Catalysis; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006305362,0.0002028672,0.0002154243,0.00005559592,0.00006826856,0.00003522475,0.00009772993,0.0001056933,0.0003462794],"category_scores_gemma":[0.00005445582,0.0001360668,0.00004946103,0.0001529223,0.0001572232,0.0002873974,0.000051795,0.0001060646,0.00003634999],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000161875,"about_ca_system_score_gemma":0.00004505409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008477557,"about_ca_topic_score_gemma":0.00007804683,"domain_scores_codex":[0.9989865,0.000004083619,0.0001684491,0.0003820764,0.0001948311,0.0002639975],"domain_scores_gemma":[0.9991623,0.0001670012,0.0001188601,0.0003563305,0.00007462958,0.0001208986],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006935995,0.00003656716,0.001671804,0.00003409441,0.0001407808,0.00001258423,0.0001943634,2.674664e-7,0.9922878,0.00008724679,0.001324127,0.004141037],"study_design_scores_gemma":[0.001127666,0.00002713094,0.0005359761,0.000117849,0.00008965571,0.0001688542,0.0001195768,0.000003725643,0.9796378,0.0003603923,0.01756484,0.000246539],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9264649,0.0002769539,0.0001274511,0.0006030051,0.00002518206,0.00007703462,0.00002100876,0.0001501212,0.0722544],"genre_scores_gemma":[0.9805821,0.0001368182,0.0001247172,0.00003826089,0.0001801888,0.00003070388,0.00002588837,0.00003696661,0.01884442],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05411719,"threshold_uncertainty_score":0.5548642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168971867857655,"score_gpt":0.2161469984148462,"score_spread":0.2044572797362697,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}