{"id":"W4229864351","doi":"10.1002/ange.201607522","title":"Stereo‐ and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"European Research Council","keywords":"Alkyne; Regioselectivity; Chemistry; Radical; Stereospecificity; Hydride; Radical initiator; Reaction mechanism; Medicinal chemistry; Stereochemistry; Photochemistry; Metal; Catalysis; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001513994,0.0002692167,0.0001565098,0.0001209472,0.0001265102,0.0002042914,0.0003112745,0.000198932,0.001508818],"category_scores_gemma":[0.0001726619,0.0001537107,0.0001498055,0.00007280294,0.0002689378,0.0002011777,0.0004432514,0.0002663057,0.0004411089],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002963552,"about_ca_system_score_gemma":0.0001431459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005537099,"about_ca_topic_score_gemma":0.001113631,"domain_scores_codex":[0.999882,0.00001407284,0.000008856447,0.00002610042,0.00002679846,0.00004218475],"domain_scores_gemma":[0.9999458,0.000008849936,0.00001211444,0.00001245615,0.000008129465,0.00001260748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001466666,0.00002191703,0.0002403293,0.0001184903,0.00001920299,0.0002354681,0.0001010178,0.0004249309,0.9914445,0.00126618,0.000299316,0.005682028],"study_design_scores_gemma":[0.00001532107,0.00006570082,0.0003676394,0.000002593662,0.000006247148,0.00009472293,0.00001097009,0.0004049288,0.9977021,0.00005489635,0.001270284,0.000004532137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875959,0.0005014018,0.003206639,0.00008421196,0.00004639653,0.00004190518,0.0001199778,0.0001551778,0.008248383],"genre_scores_gemma":[0.9975584,0.0001714449,0.0009861846,0.00001731761,0.000004875665,0.000007012981,0.00003713725,0.00001608714,0.001201548],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001508818,"threshold_uncertainty_score":0.00504756,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168971867857655,"score_gpt":0.2161469984148462,"score_spread":0.2044572797362697,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}