{"id":"W4230341808","doi":"10.1002/ejic.201501436","title":"Long‐Lived, Emissive Excited States in Direct and Amide‐Linked Thienyl‐Substituted Ru<sup>II</sup> Complexes","year":2016,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Excited state; Homoleptic; Photochemistry; Amide; Ultrafast laser spectroscopy; Diimine; Quantum yield; Conjugated system; Quenching (fluorescence); Ligand (biochemistry); Emission spectrum; Bipyridine; Crystallography; Spectroscopy; Fluorescence; Spectral line; Crystal structure; Metal; Atomic physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001447929,0.0002202272,0.0002265927,0.0001066195,0.0001092945,0.0002436349,0.0003420785,0.0002554262,0.0008548713],"category_scores_gemma":[0.0003157308,0.0001274397,0.00008232913,0.0001141829,0.0002282489,0.0002249262,0.0001829148,0.000262522,0.0001823291],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002567686,"about_ca_system_score_gemma":0.0000728103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002557288,"about_ca_topic_score_gemma":0.0002958028,"domain_scores_codex":[0.9998966,0.00002376032,0.000005460043,0.00002491575,0.00002226768,0.00002693542],"domain_scores_gemma":[0.9998727,0.00004370953,0.00003070115,0.0000156394,0.00001804716,0.00001919532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000224049,0.00001786115,0.0001628529,0.00004454031,0.000008147397,0.00004525665,0.0000317786,0.0002037852,0.9979837,0.00007363962,0.00002970898,0.001174775],"study_design_scores_gemma":[0.00002273248,0.0003488791,0.001379879,0.000003434527,0.00001323822,0.0001190245,0.00001467279,0.0008048383,0.9967697,0.00001820078,0.0005013322,0.000004271712],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986641,0.0002072995,0.0005576725,0.000008518235,0.000001988364,0.000004363453,0.00002082519,0.00001986909,0.0005153278],"genre_scores_gemma":[0.998642,0.0001015805,0.0006303508,0.000008783929,0.00000135004,0.000006945029,0.00005324109,0.00001050715,0.0005451932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008548713,"threshold_uncertainty_score":0.002859831,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01321293357053212,"score_gpt":0.2200888692093393,"score_spread":0.2068759356388072,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}