{"id":"W4230482997","doi":"10.1002/ange.201710263","title":"Solid‐State Structure of Protonated Ketones and Aldehydes","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Oxonium ion; Aldehyde; Protonation; Electrophile; Acetaldehyde; Anhydrous; Ketone; Photochemistry; Benzaldehyde; Acetone; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006298823,0.0002124775,0.00009949824,0.0001883966,0.0002083854,0.000254208,0.0002816866,0.0001799233,0.004357609],"category_scores_gemma":[0.00007390718,0.00008947587,0.00007177691,0.00009835811,0.0002615247,0.0001831304,0.0001780236,0.0002033731,0.0004436384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002665693,"about_ca_system_score_gemma":0.0001105497,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007195532,"about_ca_topic_score_gemma":0.00075026,"domain_scores_codex":[0.9999673,0.000003661797,0.00000135044,0.000005332296,0.000009488354,0.00001282103],"domain_scores_gemma":[0.9999666,0.000006208965,0.000007729835,0.000003698653,0.000007791977,0.000008002573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007708257,0.00007664724,0.001238758,0.0003824783,0.00003211237,0.0008983411,0.0002770252,0.005624673,0.9681603,0.01601449,0.001088675,0.005435617],"study_design_scores_gemma":[0.0001130786,0.001269164,0.004500932,0.00003849743,0.00002338958,0.0003510836,0.000348508,0.02396628,0.9537316,0.003218689,0.0123918,0.00004695561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948419,0.0003326452,0.0006965378,0.0000437101,0.00001974269,0.000004284017,0.0001691411,0.0000306347,0.003861542],"genre_scores_gemma":[0.9985964,0.000107414,0.0001722378,0.000005899333,0.000002067794,0.000002511794,0.0001634893,0.000003068331,0.0009469457],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004357609,"threshold_uncertainty_score":0.01457763,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01404695765646051,"score_gpt":0.2788251463265927,"score_spread":0.2647781886701322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}