{"id":"W4230482997","doi":"10.1002/ange.201710263","title":"Solid‐State Structure of Protonated Ketones and Aldehydes","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Oxonium ion; Aldehyde; Protonation; Electrophile; Acetaldehyde; Anhydrous; Ketone; Photochemistry; Benzaldehyde; Acetone; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002742005,0.00008977535,0.0001561221,0.00002785075,0.0001019016,0.00003822467,0.0001182126,0.00005201536,0.0001277225],"category_scores_gemma":[0.00009629398,0.00007739408,0.0000424233,0.00003286385,0.00007277152,0.0001325232,0.00006131736,0.00008223219,0.000002818656],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000110933,"about_ca_system_score_gemma":0.00001033732,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007959241,"about_ca_topic_score_gemma":0.00003229811,"domain_scores_codex":[0.9995365,0.000001848488,0.0001370302,0.0001339119,0.00008495509,0.0001058088],"domain_scores_gemma":[0.9994571,0.00002055876,0.0001120017,0.0003010051,0.00005758764,0.0000517682],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006615617,0.0000101566,0.001195466,0.00004556408,0.00003975241,0.000001063395,0.0001021742,0.00001476921,0.9978142,0.0000683704,0.0001585745,0.0005433446],"study_design_scores_gemma":[0.0002395217,0.000005062655,0.003797965,0.0000245599,0.00002171953,0.00000433068,0.00001815257,0.000127483,0.992745,0.0002222049,0.002703743,0.0000903023],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976326,0.00008463213,0.00005741493,0.0001475494,0.00003661155,0.0001077966,0.00005166122,0.00003677533,0.001844908],"genre_scores_gemma":[0.998723,0.00004048805,0.0001566762,0.00001360215,0.00004356753,0.000008556719,0.00003326765,0.00001150632,0.0009693544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005069194,"threshold_uncertainty_score":0.3156039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01404695765646051,"score_gpt":0.2788251463265927,"score_spread":0.2647781886701322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}