{"id":"W4230571081","doi":"10.1002/ange.201604429","title":"Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross‐Coupling of Primary Aryl Amines with Aryl Halides","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Aryl; Iridium; Halide; Nickel; Chemistry; Primary (astronomy); Catalysis; Photoredox catalysis; Coupling reaction; Coupling (piping); Combinatorial chemistry; Photochemistry; Organic chemistry; Materials science; Photocatalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000114211,0.0002725019,0.0003833348,0.00002656416,0.0001627905,0.00004023406,0.000293125,0.0001656897,0.00007974412],"category_scores_gemma":[0.0002781292,0.0001507233,0.0001492865,0.0001834208,0.0006446762,0.0001780493,0.00008277726,0.0001597032,0.000002705521],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000153059,"about_ca_system_score_gemma":0.00008250226,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001474678,"about_ca_topic_score_gemma":0.00001626229,"domain_scores_codex":[0.9985726,0.000001041412,0.0003226746,0.0004684787,0.000273826,0.000361386],"domain_scores_gemma":[0.9977443,0.001185542,0.0002196165,0.0004962129,0.0002147847,0.0001395907],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002728582,0.00008532597,0.001812181,0.0002267811,0.0002999213,0.000002490958,0.00008542555,0.000001909984,0.9959038,0.00001371465,0.0008843453,0.000411174],"study_design_scores_gemma":[0.001179065,0.00003153946,0.0005690391,0.0001909304,0.000233206,0.00001733394,0.00008438268,0.00002333011,0.9952972,0.0002561146,0.00187166,0.0002461893],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962401,0.001027906,0.0001598615,0.0005209859,0.00003100237,0.0002202139,0.0001511336,0.00007316002,0.001575649],"genre_scores_gemma":[0.997091,0.0002482749,0.0002889271,0.00005412593,0.0002008041,0.0002818598,0.00006218303,0.00005163543,0.001721175],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001243142,"threshold_uncertainty_score":0.6146318,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0141958199661016,"score_gpt":0.2430334251627264,"score_spread":0.2288376051966248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}