{"id":"W4230690006","doi":"10.1021/jp0535902","title":"Atmospheric Chemistry of CF<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>OH:  Kinetics, Mechanisms and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NO<i><sub>X</sub></i>","year":2005,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Kinetics; Chemistry; Atmospheric chemistry; Chemical reaction kinetics; Chemical kinetics; Radical; Atom (system on chip); Organic chemistry; Physics; Ozone","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001772825,0.000456298,0.0001626922,0.0001653777,0.000333955,0.0002503798,0.0002826222,0.0006048027,0.001615999],"category_scores_gemma":[0.0001854838,0.00009388089,0.0002321623,0.0001204368,0.0002230739,0.0003315649,0.000172173,0.0003269123,0.0001760973],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007772679,"about_ca_system_score_gemma":0.0003490174,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01378116,"about_ca_topic_score_gemma":0.011999,"domain_scores_codex":[0.9998921,0.000006754592,0.000002485743,0.00003083321,0.00004282886,0.00002496409],"domain_scores_gemma":[0.9999311,0.00001569261,0.00001377488,0.00000500441,0.00002596991,0.000008442289],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001860184,0.00001672769,0.00709653,0.0001522113,0.00001730532,0.0000759254,0.00004803997,0.0003647307,0.9878036,0.0001608369,0.0002864037,0.003791648],"study_design_scores_gemma":[0.00005001674,0.0004889472,0.1009982,0.00001709121,0.00004329401,0.0003349571,0.00008462463,0.002394406,0.8900852,0.000249981,0.005227039,0.00002616361],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915293,0.002042848,0.0023976,0.0001063593,0.00005627226,0.00005635507,0.0008123682,0.00008987052,0.002908954],"genre_scores_gemma":[0.9968989,0.0004399583,0.0009796319,0.00004437989,0.00001259657,0.00001714874,0.000404266,0.00001349256,0.00118973],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01378116,"threshold_uncertainty_score":0.02740186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01015644815777413,"score_gpt":0.2311430801074047,"score_spread":0.2209866319496306,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}