{"id":"W4230697413","doi":"10.1093/oso/9780199965724.003.0021","title":"New Methods for Carbon-Carbon Bond Construction","year":2013,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Stereocenter; Nitrile; Triple bond; Wittig reaction; Stereochemistry; Organic chemistry; Medicinal chemistry; Catalysis; Double bond; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008619419,0.001159088,0.0005822828,0.001883669,0.001096239,0.0006562443,0.001336137,0.0009694716,0.01058417],"category_scores_gemma":[0.0007424951,0.0007519471,0.0005817963,0.001219443,0.0007832383,0.002302947,0.002259834,0.003909177,0.005348177],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009615871,"about_ca_system_score_gemma":0.0004540923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004364057,"about_ca_topic_score_gemma":0.00105586,"domain_scores_codex":[0.9991627,0.00010002,0.00005683964,0.0001861293,0.0003788473,0.0001154708],"domain_scores_gemma":[0.9997666,0.00004773853,0.0000229353,0.00007712721,0.00005861673,0.00002700287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001756987,0.0005780142,0.0003558135,0.002972694,0.0002215582,0.001045186,0.0008710181,0.003229393,0.2922492,0.2790048,0.04528053,0.3740161],"study_design_scores_gemma":[0.0001475638,0.0005720006,0.0003577724,0.0002318887,0.00005827843,0.001273591,0.0001110345,0.00465613,0.304291,0.04147214,0.6466666,0.0001620543],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.04644697,0.0667936,0.6828775,0.003785047,0.005230911,0.001649482,0.002080979,0.002354412,0.1887812],"genre_scores_gemma":[0.4173734,0.1007164,0.3528608,0.003050428,0.0009486917,0.003528397,0.003078651,0.0007357732,0.1177074],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.01058417,"threshold_uncertainty_score":0.0354076,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01809153994530742,"score_gpt":0.2391380670172281,"score_spread":0.2210465270719207,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}