{"id":"W4232045433","doi":"10.1002/ange.200790249","title":"Metal‐Free Catalytic Hydrogenation","year":2007,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.001110249,0.0005708649,0.0005912108,0.0004141646,0.0002626778,0.0001157345,0.0009427802,0.0006050311,0.00262139],"category_scores_gemma":[0.0007826679,0.0006142925,0.0005639175,0.001736768,0.0001852729,0.0002840113,0.0003192181,0.0005139481,0.002400786],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005791091,"about_ca_system_score_gemma":0.0001605922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001082246,"about_ca_topic_score_gemma":0.00004673082,"domain_scores_codex":[0.9961663,0.00001966457,0.0009371867,0.0008539156,0.001079316,0.00094355],"domain_scores_gemma":[0.9969124,0.0002672458,0.0004712633,0.00153387,0.0002869742,0.0005282398],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002058192,0.001285638,0.001696924,0.0008515203,0.004368661,0.0005731165,0.002304398,0.00002060434,0.8835739,0.001143451,0.07058035,0.03339566],"study_design_scores_gemma":[0.0011636,0.00001681665,0.00004592619,0.00003871302,0.000921085,0.00002094487,0.0003502389,0.00006096311,0.8147114,0.0002470456,0.1818577,0.0005655608],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3075424,0.06225848,0.001833838,0.002038845,0.00197247,0.0005643378,0.0006470572,0.000782017,0.6223606],"genre_scores_gemma":[0.9741231,0.0007010915,0.0001889545,0.0005115516,0.001660697,0.00001767152,0.001621902,0.0001071856,0.02106782],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6665807,"threshold_uncertainty_score":0.9996309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01517772397375009,"score_gpt":0.2479535915698833,"score_spread":0.2327758675961333,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}