{"id":"W4232045433","doi":"10.1002/ange.200790249","title":"Metal‐Free Catalytic Hydrogenation","year":2007,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002812508,0.0004716892,0.0003454297,0.0002539575,0.0003494213,0.0004758275,0.001110562,0.0006734103,0.004604394],"category_scores_gemma":[0.0002904775,0.0002982111,0.0003123715,0.0002529127,0.0003261695,0.0007272006,0.0008271478,0.0008737505,0.001602135],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004777803,"about_ca_system_score_gemma":0.0002130041,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005223819,"about_ca_topic_score_gemma":0.0008775949,"domain_scores_codex":[0.9997012,0.00003132096,0.00001924615,0.00007251308,0.0001035739,0.00007220105],"domain_scores_gemma":[0.9999256,0.00001366329,0.000007735889,0.00002900838,0.00001272718,0.00001115154],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004540266,0.0001497769,0.000198721,0.001470427,0.0001674762,0.0003332295,0.0001707481,0.001974772,0.904872,0.01503519,0.008084059,0.06708959],"study_design_scores_gemma":[0.00004860453,0.0001114199,0.0003237314,0.00001766287,0.00003586985,0.0001275756,0.00001655126,0.002034971,0.956795,0.001662525,0.03879962,0.0000266181],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7912849,0.02903597,0.07906238,0.001667616,0.002152536,0.000238095,0.002355648,0.002050622,0.09215219],"genre_scores_gemma":[0.9657371,0.004938133,0.007454766,0.0002146999,0.00009225044,0.00005999188,0.001101106,0.0001114656,0.02029056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004604394,"threshold_uncertainty_score":0.01540327,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01517772397375009,"score_gpt":0.2479535915698833,"score_spread":0.2327758675961333,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}