{"id":"W4232126560","doi":"10.1002/1097-4601(2000)32:8<478::aid-kin5>3.3.co;2-j","title":"Kinetics of the gas‐phase reactions of Cl atom with selected C2–C5 unsaturated hydrocarbons at 283 &lt; T &lt; 323 K","year":2000,"lang":"en","type":"article","venue":"International Journal of Chemical Kinetics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Gas phase; Kinetics; Atom (system on chip); Phase (matter); Medicinal chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004434844,0.0002134981,0.0003245445,0.00007166937,0.00002220589,0.00002140425,0.0007023702,0.0001918144,0.001189679],"category_scores_gemma":[0.000131529,0.0001504579,0.0002049238,0.0003008013,0.0002318115,0.00004876885,0.00005974749,0.0005321183,0.000001701443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001659768,"about_ca_system_score_gemma":0.00007612578,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006820209,"about_ca_topic_score_gemma":0.000006790883,"domain_scores_codex":[0.99787,0.00002944135,0.0008112494,0.0001655019,0.0009243739,0.00019948],"domain_scores_gemma":[0.9980894,0.0000995862,0.0007259138,0.0002836776,0.0006799366,0.0001215015],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008274602,0.0003856866,0.0002434459,0.00002270461,0.0003418511,0.00003868387,0.00009431703,0.0002791744,0.9966519,0.0002250267,0.0003950821,0.0004946064],"study_design_scores_gemma":[0.001916002,0.000154484,0.0002107648,0.0002113819,0.000149059,0.0007338796,0.00001087544,0.0004452219,0.9869997,0.0004581528,0.008565661,0.0001448534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926734,0.0001454574,0.0002001396,0.0006603403,0.0001361995,0.00004760243,0.00007733251,0.00001246925,0.006047091],"genre_scores_gemma":[0.997861,0.0000908788,0.00129191,0.00006231417,0.0002383734,0.000001205566,0.00003588826,0.00002837728,0.0003900923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009652298,"threshold_uncertainty_score":0.9997234,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00439066924813662,"score_gpt":0.2399517138598375,"score_spread":0.2355610446117009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}