{"id":"W4232318685","doi":"10.1002/ange.201711531","title":"Silver(I)‐Catalyzed Widely Applicable Aerobic 1,2‐Diol Oxidative Cleavage","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Excellence Research Chairs, Government of Canada; Canada Foundation for Innovation","keywords":"Oxidative cleavage; Catalysis; Oxidative phosphorylation; Cleavage (geology); Stoichiometry; Chemistry; Oxygen; Bond cleavage; Diol; Combinatorial chemistry; Photochemistry; Organic chemistry; Materials science; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001359437,0.0004412084,0.0004211984,0.00004425466,0.0003055074,0.00007835332,0.0005709499,0.0003021624,0.00876693],"category_scores_gemma":[0.0001869179,0.0004532451,0.0001774255,0.0004219106,0.0004708129,0.0002086014,0.0002521141,0.0004310212,0.001592009],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003150178,"about_ca_system_score_gemma":0.0001216198,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007362763,"about_ca_topic_score_gemma":0.00002848307,"domain_scores_codex":[0.9977848,0.00001044934,0.0004047102,0.000804445,0.0003465385,0.0006490651],"domain_scores_gemma":[0.9980721,0.0001476486,0.0002378942,0.001044131,0.0002110702,0.0002871196],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005148835,0.0001334796,0.0004118181,0.00006923889,0.0001305059,0.00001132492,0.0002387326,2.397982e-7,0.9719868,0.00003552614,0.02661302,0.0003178345],"study_design_scores_gemma":[0.0008488511,0.0000178237,0.00006005246,0.00005011907,0.00006788893,0.00004263396,0.000414677,0.000008814577,0.9262853,0.0001963938,0.07153085,0.0004766269],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7044701,0.0001367072,0.000120889,0.0002670665,0.00009991421,0.0001323728,0.0001072675,0.0004472497,0.2942185],"genre_scores_gemma":[0.9820045,0.00003319556,0.0006569436,0.0001622951,0.001244107,0.00008721936,0.0002984254,0.0000978942,0.01541538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2788031,"threshold_uncertainty_score":0.9997919,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01748150997537999,"score_gpt":0.2504033621442683,"score_spread":0.2329218521688883,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}