{"id":"W4232395397","doi":"10.1002/ange.200353108","title":"Stable Cubic Phosphorus‐Containing Radicals","year":2004,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge; University of Calgary","funders":"","keywords":"Chemistry; Radical; Phosphorus; Medicinal chemistry; Crystal structure; Stereochemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001198,0.0002506439,0.0003212705,0.00004375636,0.0001629595,0.0001106675,0.0003344896,0.0001570946,0.01071863],"category_scores_gemma":[0.00009450784,0.0002486198,0.0001312698,0.0001946643,0.0000718744,0.0001896066,0.00009606706,0.0001892038,0.0001860632],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001996591,"about_ca_system_score_gemma":0.0001230099,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000055379,"about_ca_topic_score_gemma":0.000003157996,"domain_scores_codex":[0.9985544,0.000004686868,0.000351047,0.0003904871,0.0002833012,0.0004160585],"domain_scores_gemma":[0.999099,0.00006602905,0.0001416652,0.0004458316,0.00006279063,0.0001846573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000221903,0.0001291639,0.0009031923,0.00003423065,0.00007077002,0.00001664875,0.0002422321,0.000003666006,0.9966592,0.0005244972,0.0003346038,0.001059652],"study_design_scores_gemma":[0.0007278758,0.00001390364,0.0003033579,0.00006359989,0.00003240071,0.00002157275,0.0001896592,0.000001855424,0.8876193,0.000408215,0.1103334,0.0002849202],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.927471,0.0008685022,0.0001920384,0.0006961513,0.000122595,0.00004791516,0.00002975699,0.0002511275,0.07032094],"genre_scores_gemma":[0.9944336,0.0002354562,0.0003860958,0.0004540932,0.0003686633,0.00002104026,0.0001033958,0.00005833738,0.003939249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1099988,"threshold_uncertainty_score":0.9999966,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01908336735622481,"score_gpt":0.231541998987202,"score_spread":0.2124586316309772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}