{"id":"W4232851263","doi":"10.1002/chin.200732257","title":"Tetrahedral Intermediates Derived from Carbonyl Compounds, Pentacoordinate Intermediates Derived from Phosphoryl and Sulfonyl Compounds, and Concerted Paths to Avoid Them","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Sulfonyl; Tetrahedron; Combinatorial chemistry; Computational chemistry; Stereochemistry; Organic chemistry; Crystallography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002812096,0.0009827063,0.001131239,0.0001378857,0.0003184717,0.0004184656,0.0008877367,0.0005096502,0.001384268],"category_scores_gemma":[0.0003886601,0.0009814537,0.0001847376,0.0002687365,0.0007666535,0.0004436336,0.0009510514,0.0006970115,0.0001222923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00045818,"about_ca_system_score_gemma":0.0001189721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002516558,"about_ca_topic_score_gemma":0.0005492364,"domain_scores_codex":[0.9960519,0.000005277663,0.001109779,0.001119214,0.0005487066,0.001165127],"domain_scores_gemma":[0.9959154,0.001730712,0.0004139704,0.0008773687,0.0001781767,0.0008843623],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005752064,0.0001250852,0.057708,0.0001199627,0.0003620567,0.00007624459,0.006893235,8.3591e-8,0.895587,0.000009975469,0.001719996,0.03682322],"study_design_scores_gemma":[0.002310258,0.00005618202,0.03861517,0.0003786586,0.0001629754,0.00003598919,0.005500914,0.0000811943,0.9477519,0.0005118195,0.003470409,0.001124584],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9728811,0.001653434,0.00001106534,0.000252083,0.0004976253,0.0003136648,0.0007431935,0.0003984921,0.02324934],"genre_scores_gemma":[0.9965089,0.0003922713,0.0007153622,0.0004996355,0.0004214511,0.00004978216,0.0006856569,0.0001528158,0.0005741043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05216491,"threshold_uncertainty_score":0.9995286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145620310237061,"score_gpt":0.2172753270372734,"score_spread":0.2058191239349028,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}