{"id":"W4233025502","doi":"10.1002/ange.201804183","title":"Nitrogen‐Based Lewis Acids Derived from Phosphonium Diazo Cations","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Phosphonium; Medicinal chemistry; Lewis acids and bases; Diazo; Stereochemistry; Cleavage (geology); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001275173,0.0003582978,0.0001615825,0.0001334434,0.0001112539,0.0001539659,0.0003116781,0.0002635796,0.001987085],"category_scores_gemma":[0.0001765324,0.0001643189,0.0001233087,0.00008971672,0.0001839276,0.0002419425,0.000270097,0.0004061845,0.0005117723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001993528,"about_ca_system_score_gemma":0.0002013615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003313238,"about_ca_topic_score_gemma":0.0008564901,"domain_scores_codex":[0.9999161,0.00001438588,0.000004448266,0.00001457515,0.00002628847,0.00002425811],"domain_scores_gemma":[0.9999472,0.00001280032,0.00001135224,0.000006372397,0.000006665089,0.00001569155],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007046117,0.000006932714,0.00002872533,0.00009457528,0.000003164981,0.00006004123,0.00001260278,0.00008532953,0.9981135,0.000312157,0.00007031202,0.001142219],"study_design_scores_gemma":[0.00001652513,0.0001336948,0.0001913698,0.00000507506,0.000005389456,0.00009670267,0.000006458225,0.0002535098,0.9964238,0.0001148583,0.002747907,0.000004840015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9630487,0.001563899,0.01615293,0.0002252571,0.0001599782,0.0001560727,0.0006113607,0.0003824834,0.01769939],"genre_scores_gemma":[0.9857518,0.000737798,0.007509183,0.0000898049,0.00001778497,0.00004112321,0.0004854233,0.00003068113,0.005336429],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001987085,"threshold_uncertainty_score":0.006647408,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01433818270036195,"score_gpt":0.235937452089599,"score_spread":0.2215992693892371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}