{"id":"W4233213846","doi":"10.1002/ange.201003074","title":"Catalytic Solvolysis of Ammonia Borane","year":2010,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Solvolysis; Chemistry; Borane; Ammonia borane; Ammonia; Catalysis; Medicinal chemistry; Organic chemistry; Hydrolysis; Hydrogen production","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0008193066,0.0003821096,0.0007970657,0.0001101722,0.0001363693,0.0001365907,0.0006558646,0.0003889858,0.003080684],"category_scores_gemma":[0.0002467148,0.0003576487,0.0002219031,0.0003107757,0.0004184686,0.0002566074,0.0002381414,0.0002541082,0.00210329],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003666851,"about_ca_system_score_gemma":0.0002139565,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008237572,"about_ca_topic_score_gemma":0.0001648804,"domain_scores_codex":[0.9975057,0.00004598298,0.000740115,0.0005920925,0.0004668044,0.000649337],"domain_scores_gemma":[0.9978883,0.00009683568,0.0004380498,0.001079029,0.0002091994,0.0002885344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006172097,0.0001624898,0.0001130226,0.0003020735,0.00008880418,0.0000662976,0.0006520228,0.000001173491,0.994045,0.00008756792,0.004118842,0.0003009728],"study_design_scores_gemma":[0.0005396397,0.00005996703,0.00004420487,0.00006776158,0.0003891891,0.00001538717,0.00004426963,0.000003361885,0.949974,0.0001875339,0.04830277,0.0003719266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908137,0.001925505,0.00001588357,0.0002100406,0.004202432,0.0002467339,0.0004357558,0.00007483784,0.002075165],"genre_scores_gemma":[0.9956803,0.0003008759,0.0008944339,0.0001232378,0.001316742,0.00002292543,0.0001119217,0.00005638247,0.00149314],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04418393,"threshold_uncertainty_score":0.9998875,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01224354353973482,"score_gpt":0.2457050933211473,"score_spread":0.2334615497814125,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}