{"id":"W4233280633","doi":"10.1002/chin.200016308","title":"ChemInform Abstract: Carbocations","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Service (business); Nanotechnology; Medicinal chemistry; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00006238351,0.0002334644,0.0001886992,0.00003075982,0.00009478912,0.00005430797,0.0003367918,0.0002437263,0.1803462],"category_scores_gemma":[0.00008577427,0.0002384859,0.0001414943,0.0001632779,0.00006647858,0.0002845699,0.00003726215,0.0003266861,0.002175899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002250631,"about_ca_system_score_gemma":0.00007973854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003319677,"about_ca_topic_score_gemma":0.000002764045,"domain_scores_codex":[0.9986755,6.116969e-9,0.0003966526,0.0002456373,0.0002749542,0.0004072685],"domain_scores_gemma":[0.9989633,0.00006722369,0.00009416945,0.0005581664,0.00006481394,0.0002523595],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001650999,0.00005246979,0.000003825478,0.0000685265,0.00001950221,0.000002182254,0.0002053888,2.00087e-7,0.1232955,0.0002634061,0.01880263,0.8572698],"study_design_scores_gemma":[0.0002263339,0.000002182708,0.00002043546,0.00002007448,0.00001093298,0.00002039605,0.00009848562,0.000008414582,0.6067417,0.0002177772,0.3924494,0.0001838408],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.03103931,0.00003509377,7.732007e-8,0.0001139446,0.00004826401,0.00004815227,0.00002125494,0.0003174767,0.9683764],"genre_scores_gemma":[0.5713613,0.00007161351,0.00004668257,0.0002240005,0.0002779624,0.00006193916,0.0002081823,0.00003466811,0.4277136],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.857086,"threshold_uncertainty_score":0.998601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01273973170789663,"score_gpt":0.2405145908120631,"score_spread":0.2277748591041665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}