{"id":"W4233305813","doi":"10.1002/ange.201907486","title":"Carboxyboronate: A Versatile C1 Building Block","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Carbonylation; Derivatization; Nucleophile; Combinatorial chemistry; Reactivity (psychology); Carbon monoxide; Palladium; Ruthenium; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000781548,0.0001984841,0.0002172046,0.00003960445,0.00008396556,0.00006988298,0.0002397528,0.0001592635,0.002622375],"category_scores_gemma":[0.00006987942,0.0002126276,0.0001320304,0.000148804,0.00005847862,0.0001165244,0.0001109797,0.0002711398,0.0004784853],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002366804,"about_ca_system_score_gemma":0.00007722854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002444568,"about_ca_topic_score_gemma":0.00001692634,"domain_scores_codex":[0.9987928,2.590995e-7,0.0002044324,0.0003947375,0.0002452556,0.000362472],"domain_scores_gemma":[0.9990106,0.000107247,0.0000879076,0.0006168828,0.00006535465,0.0001120467],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001708329,0.00004001584,0.002685741,0.00008242912,0.00004922629,0.000009027617,0.0001945512,0.00003530068,0.9949145,0.00004740826,0.001793048,0.0001316147],"study_design_scores_gemma":[0.0006617188,0.000006112748,0.0001460424,0.00005600595,0.00004085104,0.00003330803,0.0001746662,0.00007969297,0.9522827,0.00006431656,0.04621071,0.0002438637],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9655799,0.0002609256,0.0000010692,0.0001082843,0.0002316978,0.00006509331,0.00004276544,0.0002264467,0.03348386],"genre_scores_gemma":[0.9893888,0.00002476594,0.00005541389,0.00005696093,0.0002614075,0.00001860836,0.00006700879,0.00004773616,0.01007927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04441767,"threshold_uncertainty_score":0.9982893,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01011535536410731,"score_gpt":0.2481053096005649,"score_spread":0.2379899542364576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}