{"id":"W4233305813","doi":"10.1002/ange.201907486","title":"Carboxyboronate: A Versatile C1 Building Block","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Carbonylation; Derivatization; Nucleophile; Combinatorial chemistry; Reactivity (psychology); Carbon monoxide; Palladium; Ruthenium; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443249,0.0005474808,0.0002185744,0.0002669417,0.0002023734,0.0002710269,0.0003858583,0.0003614553,0.002369931],"category_scores_gemma":[0.00009914545,0.0001662505,0.0001403713,0.0001837376,0.000167137,0.0003115976,0.0003382576,0.0004471409,0.001300638],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003392911,"about_ca_system_score_gemma":0.0002996363,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008086964,"about_ca_topic_score_gemma":0.001015842,"domain_scores_codex":[0.9998771,0.00001804334,0.000007543879,0.00002924413,0.00002586983,0.00004224968],"domain_scores_gemma":[0.999929,0.000008310435,0.00001863907,0.000007018392,0.00001048536,0.00002664813],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001390194,0.0000349698,0.00009730976,0.0001504191,0.000008988039,0.0001582132,0.00002693049,0.0004175707,0.9906453,0.001831346,0.0003034553,0.006186516],"study_design_scores_gemma":[0.00002705195,0.0003974884,0.0006014968,0.00001464538,0.00001407405,0.0003411202,0.000008629723,0.0007946747,0.9842321,0.0001490505,0.01340223,0.00001745438],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9377069,0.009624327,0.01903557,0.0005969082,0.0001659625,0.0001803789,0.001554172,0.0008404094,0.03029533],"genre_scores_gemma":[0.9871859,0.002049378,0.00616597,0.0001096843,0.00001666902,0.00004272079,0.0004367002,0.00003543151,0.003957542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002369931,"threshold_uncertainty_score":0.007928252,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01011535536410731,"score_gpt":0.2481053096005649,"score_spread":0.2379899542364576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}