{"id":"W4233518296","doi":"10.1139/v10-008","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes — Part IX. Synthesis and characterization of a series of 1,4-di[2-aryl-1-diazenyl]-2,6-dimethylpiperazines","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Triazene; Piperazine; Stereocenter; Aryl; Methylene; Mass spectrum; Ring (chemistry); Proton NMR; Heteronuclear single quantum coherence spectroscopy; Mass spectrometry; Azole; Nuclear magnetic resonance spectroscopy; Carbon-13 NMR; Stereochemistry; Spectroscopy; Medicinal chemistry; Organic chemistry; Alkyl; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001919108,0.000197766,0.0005862469,0.00009451185,0.00004917288,0.00001699985,0.0002487981,0.000241881,0.0009664147],"category_scores_gemma":[0.0008865787,0.0001886837,0.0001670018,0.0001693737,0.0003387621,0.000198535,0.00002167875,0.0003094435,2.443758e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002861435,"about_ca_system_score_gemma":0.000632644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003065875,"about_ca_topic_score_gemma":0.0001795117,"domain_scores_codex":[0.998616,0.000009223641,0.0007975757,0.0001584792,0.0001980943,0.0002205928],"domain_scores_gemma":[0.9977472,0.0001848069,0.0009371715,0.0002715282,0.0004457547,0.0004135084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007288415,0.00004466273,0.00171737,0.0005425548,0.00009587269,0.00001049325,0.0002405068,0.000001056104,0.9949068,0.00003371445,0.0000393021,0.002294808],"study_design_scores_gemma":[0.0003831352,0.00002209229,0.000540979,0.0003378642,0.00008594081,0.0001787224,0.0003848734,0.000006415302,0.9938139,0.0001701724,0.003922245,0.0001536638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978184,0.0002280188,0.00001399638,0.0001826973,0.000128097,0.00003438332,0.0002426553,0.000005334358,0.001346479],"genre_scores_gemma":[0.9989006,0.000219778,0.0003417757,0.000009210818,0.0002101353,0.000004545608,0.00002013672,0.00002495557,0.0002688933],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003882943,"threshold_uncertainty_score":0.9999468,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00822417005501848,"score_gpt":0.2003077294869919,"score_spread":0.1920835594319734,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}