{"id":"W4233518296","doi":"10.1139/v10-008","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes — Part IX. Synthesis and characterization of a series of 1,4-di[2-aryl-1-diazenyl]-2,6-dimethylpiperazines","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Triazene; Piperazine; Stereocenter; Aryl; Methylene; Mass spectrum; Ring (chemistry); Proton NMR; Heteronuclear single quantum coherence spectroscopy; Mass spectrometry; Azole; Nuclear magnetic resonance spectroscopy; Carbon-13 NMR; Stereochemistry; Spectroscopy; Medicinal chemistry; Organic chemistry; Alkyl; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001184128,0.0002719855,0.0002353603,0.0002650723,0.0001061294,0.000218697,0.0003146206,0.0002143042,0.001715198],"category_scores_gemma":[0.0001763015,0.0001357932,0.0002229044,0.0002420433,0.0001587938,0.0001749447,0.0001648009,0.0003385767,0.0005531726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002564027,"about_ca_system_score_gemma":0.0001735739,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004385748,"about_ca_topic_score_gemma":0.0008794722,"domain_scores_codex":[0.9998788,0.00001721728,0.00001302675,0.00002329478,0.00003562268,0.0000320226],"domain_scores_gemma":[0.9999222,0.000008211131,0.00002455994,0.00001074609,0.00001552477,0.00001878721],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007204498,0.00002343676,0.00008111932,0.00007643426,0.000005513799,0.00004752542,0.00001673282,0.000127347,0.9967654,0.0001415268,0.00006120242,0.002581811],"study_design_scores_gemma":[0.00001707018,0.0006323412,0.001258064,0.000009974308,0.0000167813,0.00016239,0.00001869967,0.0003119128,0.9925675,0.00004138256,0.004957348,0.000006520876],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9796566,0.005200649,0.005978609,0.00008871636,0.0000689692,0.0001335986,0.0008753102,0.0001985153,0.007798858],"genre_scores_gemma":[0.9814454,0.003506996,0.007507146,0.00006662942,0.00001626286,0.000105086,0.001019369,0.00004403079,0.006289068],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001715198,"threshold_uncertainty_score":0.00573796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00822417005501848,"score_gpt":0.2003077294869919,"score_spread":0.1920835594319734,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}