{"id":"W4233532531","doi":"10.1002/ange.201412357","title":"Copper‐Catalyzed Intermolecular Carboetherification of Unactivated Alkenes by Alkyl Nitriles and Alcohols","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Alkyl; Chemistry; Catalysis; Tertiary alcohols; Intermolecular force; Organic chemistry; Alkoxy group; Quaternary carbon; Medicinal chemistry; Enantioselective synthesis; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000254821,0.0001820589,0.0002671492,0.00004994326,0.00003357324,0.00002641076,0.0001519426,0.0001517783,0.0002272925],"category_scores_gemma":[0.0004446789,0.000183731,0.00005927966,0.0002006951,0.0001535308,0.0001071217,0.00006830267,0.0001000592,0.00000635823],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008585292,"about_ca_system_score_gemma":0.00007728456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001916011,"about_ca_topic_score_gemma":0.000003297351,"domain_scores_codex":[0.9989189,0.0000234814,0.0003146839,0.0003170377,0.0002653438,0.0001605409],"domain_scores_gemma":[0.9989168,0.0001180917,0.0001974398,0.0003844223,0.0002367052,0.0001465564],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005863083,0.00005312025,0.001350423,0.00007685914,0.00007931951,0.000001622454,0.0002625062,0.000003987543,0.990796,0.00005654103,0.006510829,0.0007501277],"study_design_scores_gemma":[0.0009342185,0.000009750032,0.00007929371,0.00004365131,0.00006058536,0.00001603506,0.0004443646,0.00004187794,0.9802657,0.0002023323,0.01771702,0.0001851594],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825712,0.001708391,0.0009577422,0.0002190447,0.00008735174,0.0001045815,0.0001362026,0.0001066539,0.01410881],"genre_scores_gemma":[0.9966383,0.00008655163,0.0007339974,0.00006752045,0.00008008259,0.00003146409,0.0009911956,0.00003859175,0.001332299],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01406708,"threshold_uncertainty_score":0.7492333,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03415178405756766,"score_gpt":0.2839841687519463,"score_spread":0.2498323846943786,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}