{"id":"W4233633554","doi":"10.1002/ange.201709926","title":"Asymmetric Imine Hydroboration Catalyzed by Chiral Diazaphospholenes","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Dalhousie University","keywords":"Hydroboration; Enantioselective synthesis; Imine; Chemistry; Catalysis; Enantiomer; Organic chemistry; Combinatorial chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003063429,0.0004452713,0.0003891178,0.0002610957,0.0002243851,0.0003305105,0.0004880862,0.0003366062,0.002624576],"category_scores_gemma":[0.0002251644,0.0002338795,0.0002114595,0.0001538067,0.0003760556,0.0003379211,0.0005606966,0.0007432615,0.001008599],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003714743,"about_ca_system_score_gemma":0.0003042055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004417708,"about_ca_topic_score_gemma":0.001064145,"domain_scores_codex":[0.9997149,0.00004909684,0.00002031098,0.00004504451,0.00006845235,0.0001022],"domain_scores_gemma":[0.9999408,0.00001390984,0.00001182662,0.000009944566,0.00000861422,0.00001501128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001878897,0.00003884455,0.0001104404,0.0001843693,0.00001735821,0.0003256443,0.00006615657,0.0002712096,0.9906014,0.001662401,0.0003986116,0.006135662],"study_design_scores_gemma":[0.00004339949,0.00008122256,0.0002169,0.000005167014,0.000007100736,0.000154186,0.00001409032,0.0003728791,0.9949681,0.0001573157,0.003971152,0.000008507989],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9253269,0.004536144,0.02557174,0.0008856533,0.000339241,0.0002515035,0.0007419842,0.0004753691,0.0418715],"genre_scores_gemma":[0.9889039,0.001355861,0.005451319,0.00009490643,0.00002528263,0.00003502344,0.0001564053,0.00004538217,0.003931913],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002624576,"threshold_uncertainty_score":0.008780062,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01276756386816386,"score_gpt":0.248310643962175,"score_spread":0.2355430800940111,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}