{"id":"W4233653459","doi":"10.1002/chin.200618043","title":"Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides: Intramolecular Studies Leading to New Intermolecular Reactions.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intermolecular force; Aryl; Intramolecular force; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001131473,0.0003281861,0.0003558175,0.0001113996,0.0001906412,0.0001744678,0.0001592063,0.0001160518,0.00003742719],"category_scores_gemma":[0.0001897182,0.0003169492,0.0000790113,0.00032246,0.0001604779,0.0003174726,0.0001084546,0.000243795,0.0000580696],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004863654,"about_ca_system_score_gemma":0.0001185915,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009814005,"about_ca_topic_score_gemma":0.000129335,"domain_scores_codex":[0.9984584,2.19754e-8,0.0004452154,0.0004518739,0.0002676244,0.0003768729],"domain_scores_gemma":[0.9988719,0.0001196713,0.0001731443,0.0005216907,0.0001256937,0.0001879394],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001342786,0.0000609101,0.0004365407,0.0005277349,0.0003303216,0.00007504971,0.0008492505,0.0001837866,0.9701979,0.0002391235,0.006396919,0.02056815],"study_design_scores_gemma":[0.0005144958,0.00002460862,0.0001614906,0.0005140046,0.000150019,0.0002056981,0.0005050688,0.00005366082,0.9907956,0.0002308108,0.00644354,0.0004010727],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.978712,0.0008525244,0.00005324755,0.0001751218,0.0000927239,0.0001729762,0.00001583296,0.000269575,0.01965604],"genre_scores_gemma":[0.9881583,0.00005643754,0.0001300809,0.00004342274,0.0002238625,0.00004597042,0.0002087563,0.00005226897,0.01108083],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02059759,"threshold_uncertainty_score":0.9999282,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01277292305839199,"score_gpt":0.2600817519546983,"score_spread":0.2473088288963063,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}