{"id":"W4234175014","doi":"10.26434/chemrxiv-2021-mvjqq-v2","title":"Using transient equilibria (TREQ) to measure the thermodynamics of slowly assembling supramolecular systems","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Fiber-reinforced polymer composites","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Supramolecular chemistry; Thermodynamics; Chemistry; Cyanuric acid; Heat capacity; Chemical stability; Thermodynamic equilibrium; Thermal stability; Molecule; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003102889,0.0005101349,0.00067704,0.0001568075,0.0000580729,0.0002257857,0.0007862386,0.0004013271,0.00001175005],"category_scores_gemma":[0.00003959585,0.0004638684,0.0003812759,0.0003770626,0.00004580449,0.00007597722,0.0003471398,0.0007083673,0.00000467287],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002033335,"about_ca_system_score_gemma":0.0001434317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001348424,"about_ca_topic_score_gemma":0.000008668525,"domain_scores_codex":[0.9978604,0.00008066514,0.0006520536,0.0004355234,0.0005102638,0.0004610565],"domain_scores_gemma":[0.9981642,0.0001055139,0.0001284936,0.001272241,0.0001901712,0.0001393701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.000004848082,0.000007075994,0.00001437934,0.0006288904,0.0002309489,0.000008840077,0.0007849145,0.4960152,0.5020883,0.00009524305,0.0000199456,0.0001014038],"study_design_scores_gemma":[0.0001505711,0.00001098836,0.00004876605,0.00116311,0.0001939383,0.00001889717,0.0001732265,0.7545695,0.243059,0.00001518175,0.0001158618,0.0004809213],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8721134,0.00707928,0.1150302,0.00004813885,0.001548734,0.0006497225,0.00001127288,0.0002419325,0.003277287],"genre_scores_gemma":[0.997183,0.00002699867,0.002294819,0.00002525527,0.000164161,0.00005180586,0.00005085056,0.0001667158,0.00003635586],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2590293,"threshold_uncertainty_score":0.9997813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03012114663939775,"score_gpt":0.2411652459540838,"score_spread":0.211044099314686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}