{"id":"W4234620227","doi":"10.1002/ange.202010917","title":"Salt to Taste: The Critical Roles Played by Inorganic Salts in Organozinc Formation and in the Negishi Reaction","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Eli Lilly and Company","keywords":"Negishi coupling; Chemistry; Salt (chemistry); Catalysis; Nucleophile; Salt bridge; Reagent; Aryl; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001860519,0.0001414228,0.0001441241,0.00002801028,0.0001079657,0.0001299557,0.0002149455,0.0001118879,0.00006190725],"category_scores_gemma":[0.0007257178,0.0001050408,0.00002880054,0.0003601362,0.00007288576,0.0002366865,0.00007730573,0.0003938038,0.00003108579],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001259129,"about_ca_system_score_gemma":0.00003596001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001734188,"about_ca_topic_score_gemma":0.0005490801,"domain_scores_codex":[0.9990423,0.000003181048,0.0002656278,0.0002466388,0.0002069929,0.000235204],"domain_scores_gemma":[0.9992212,0.0003489942,0.00005061877,0.0002612253,0.00003505671,0.0000829266],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005405956,0.00004181227,0.0005217501,0.0000567291,0.000004619297,0.000005085386,0.004303419,0.000003040455,0.9884924,0.00001750407,0.00626645,0.0002330938],"study_design_scores_gemma":[0.0004268299,0.00001283008,0.000973828,0.000040863,0.00001917885,0.00003880888,0.003031157,0.0001135053,0.9891053,0.00007806944,0.006030093,0.0001294638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830753,0.0002072395,0.0000179394,0.01580005,0.00003142029,0.000124427,0.00004246546,0.00004948373,0.0006516649],"genre_scores_gemma":[0.9983469,0.00004637066,0.000007313333,0.001242283,0.0001551521,0.00003838936,0.000103181,0.00002030482,0.00004015697],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01527154,"threshold_uncertainty_score":0.4283439,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0165807890978341,"score_gpt":0.2635811650530069,"score_spread":0.2470003759551728,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}