{"id":"W4234736062","doi":"10.1002/ange.201706273","title":"A Concise Enantioselective Total Synthesis of (−)‐Virosaine A","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Phytochemistry and Bioactivity Studies","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Enantioselective synthesis; Cycloaddition; Chemistry; Epoxide; Nitrone; Intramolecular force; Total synthesis; Combinatorial chemistry; Furan; Halogenation; Surface modification; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002014925,0.0006679431,0.0003926295,0.000366254,0.0002735873,0.0002882756,0.0004279057,0.0002718753,0.001704894],"category_scores_gemma":[0.0001405702,0.0001945536,0.0003421902,0.0002996249,0.000201664,0.0003099724,0.0004392879,0.0005908782,0.0009853997],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002519964,"about_ca_system_score_gemma":0.0007644038,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007987966,"about_ca_topic_score_gemma":0.001281968,"domain_scores_codex":[0.9998693,0.00002384852,0.00001468868,0.00002904492,0.00002184635,0.00004125168],"domain_scores_gemma":[0.999946,0.000005758485,0.000009826304,0.00001083238,0.000009506712,0.00001808082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001205818,0.0001343319,0.0001229857,0.0004132439,0.0000489476,0.0004351716,0.0001250064,0.001852839,0.9678448,0.002413202,0.0006414598,0.02584746],"study_design_scores_gemma":[0.00009405898,0.001354087,0.00123895,0.00005103774,0.00006065346,0.0006930113,0.00004847498,0.001811762,0.961178,0.0009325877,0.03248506,0.00005229014],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8478799,0.007571092,0.09504795,0.0003502092,0.0004476334,0.0008442364,0.004453812,0.001012157,0.04239302],"genre_scores_gemma":[0.9558664,0.004145399,0.02913213,0.0001128422,0.00003373663,0.0002393172,0.001297687,0.0000814068,0.00909098],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001704894,"threshold_uncertainty_score":0.005703449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1026391819203591,"score_gpt":0.4123753393311066,"score_spread":0.3097361574107474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}