{"id":"W4234736062","doi":"10.1002/ange.201706273","title":"A Concise Enantioselective Total Synthesis of (−)‐Virosaine A","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Phytochemistry and Bioactivity Studies","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Enantioselective synthesis; Cycloaddition; Chemistry; Epoxide; Nitrone; Intramolecular force; Total synthesis; Combinatorial chemistry; Furan; Halogenation; Surface modification; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002750858,0.0001792819,0.0003385983,0.00002326206,0.0004817345,0.00001777131,0.0002847318,0.0002098308,0.0002925029],"category_scores_gemma":[0.0006964498,0.0001585032,0.0001364481,0.00004820875,0.0005316997,0.0001338313,0.0001558802,0.0003067582,0.00002147379],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003725678,"about_ca_system_score_gemma":0.00004850178,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002837283,"about_ca_topic_score_gemma":0.000008178854,"domain_scores_codex":[0.9991239,0.00004245363,0.0001863156,0.0002479584,0.0001061473,0.000293176],"domain_scores_gemma":[0.9988674,0.0003351214,0.000264468,0.0003294239,0.0001008795,0.0001027061],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003423228,0.0002621028,0.008663625,0.00008407538,0.0003385598,0.00002357755,0.0002554486,0.000001031013,0.9827272,0.00005447571,0.003983818,0.003263796],"study_design_scores_gemma":[0.0006996733,0.00004629127,0.006337004,0.00002880146,0.0001626028,0.00001696681,0.00008506102,0.0000100047,0.9834355,0.0001649246,0.008833309,0.0001798983],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9440418,0.0003590415,0.000005819037,0.0008921472,0.0002290111,0.0001527166,0.0001704338,0.00003790861,0.05411107],"genre_scores_gemma":[0.9976796,0.0001832247,0.00004547193,0.000153568,0.0002331772,0.00005987492,0.000005667455,0.00001103819,0.001628365],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05363776,"threshold_uncertainty_score":0.6463574,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1026391819203591,"score_gpt":0.4123753393311066,"score_spread":0.3097361574107474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}