{"id":"W4234799893","doi":"10.1002/ange.201902039","title":"The Arene‐Stabilized η5‐Pentamethylcyclopentadienyl Arsenic Dication [(η5‐Cp*)As(toluene)]2+","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Toluene; Dication; Medicinal chemistry; Reactivity (psychology); Fluoride; Lewis acids and bases; Cleavage (geology); Chloride; Arsenic; Stereochemistry; Molecule; Inorganic chemistry; Catalysis; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005467101,0.0002668417,0.0001121027,0.00007768435,0.0001830513,0.0002328018,0.0002332879,0.0001940734,0.002945377],"category_scores_gemma":[0.00006925558,0.0001159566,0.00008748982,0.00007152104,0.0001893107,0.0001546224,0.0002124522,0.0002171639,0.0006068028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002259289,"about_ca_system_score_gemma":0.0002034076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009693676,"about_ca_topic_score_gemma":0.0014485,"domain_scores_codex":[0.9999429,0.000005379083,0.000002744033,0.00001114368,0.00001676797,0.00002106591],"domain_scores_gemma":[0.9999704,0.000001779007,0.000007075648,0.000004577579,0.00000691571,0.000009203222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007675738,0.00000700803,0.00007688324,0.00005622184,0.0000042077,0.00007030077,0.00002204192,0.0001246574,0.997537,0.0004772572,0.0002623041,0.001285431],"study_design_scores_gemma":[0.00001137458,0.0001245097,0.0005441952,0.000002875649,0.000005532059,0.0000828895,0.00001806424,0.0004416871,0.9950812,0.00004582034,0.003635562,0.000006229252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9868453,0.0003654969,0.002978221,0.0000946739,0.0000706815,0.00002305489,0.0002935932,0.0001818275,0.009147224],"genre_scores_gemma":[0.9953408,0.0001171048,0.001088464,0.00003071242,0.000007457797,0.000008486861,0.0002502859,0.00001996347,0.003136625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002945377,"threshold_uncertainty_score":0.009853244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01044330928495929,"score_gpt":0.2379886293970585,"score_spread":0.2275453201120992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}