{"id":"W4235019392","doi":"10.22215/etd/2015-10902","title":"Development of Palladium-Catalyzed Decarboxylative Allylation of Electron-Deficient Sulfones: Method Development and Mechanistic Studies","year":2015,"lang":"en","type":"dissertation","venue":"","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Protonation; Chemistry; Palladium; Trifluoromethyl; Ligand (biochemistry); Hydride; Kinetic isotope effect; Allene; Catalysis; Medicinal chemistry; Deuterium; Photochemistry; Organic chemistry; Metal; Ion; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001478423,0.0005136653,0.001029045,0.0003509004,0.0001193719,0.00001757905,0.0002044531,0.0003496522,0.0002400434],"category_scores_gemma":[0.0009841233,0.0004898141,0.00009541115,0.0003851372,0.00005686547,0.00007123326,0.0001007061,0.0001982926,0.000005647468],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006061626,"about_ca_system_score_gemma":0.002022317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002403445,"about_ca_topic_score_gemma":0.000404907,"domain_scores_codex":[0.996339,0.00007220946,0.001615302,0.0006602567,0.001020067,0.0002932228],"domain_scores_gemma":[0.9959253,0.0005747036,0.001275418,0.0003430923,0.001760123,0.0001213356],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001007635,0.00047551,0.0001313852,0.007289411,0.003773587,0.00000331424,0.0665654,0.0003820753,0.8656282,0.01312838,0.0003293468,0.04128576],"study_design_scores_gemma":[0.0008206489,0.00002129844,0.000280367,0.0004210864,0.0003399993,0.000004352719,0.01404631,0.0002824253,0.9791836,0.001561228,0.00250859,0.0005300987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8851513,0.004075157,0.09252428,0.00001464736,0.0006888284,0.000673119,0.0000541341,0.0001323316,0.01668624],"genre_scores_gemma":[0.08495348,0.0001917908,0.8888453,0.00001439373,0.0001201642,0.0003077167,0.009735695,0.0001650681,0.01566636],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.8001978,"threshold_uncertainty_score":0.9997553,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05418959416270851,"score_gpt":0.3686810061161154,"score_spread":0.3144914119534069,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}