{"id":"W4235063745","doi":"10.1002/ange.201712211","title":"Palladium‐Catalyzed Formal Cross‐Coupling of Diaryl Ethers with Amines: Slicing the 4‐<i>O</i>‐5 Linkage in Lignin Models","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Lignin and Wood Chemistry","field":"Engineering","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Ether; Lignin; Bond cleavage; Organic chemistry; Silyl ether; Catalysis; Silylation","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002040815,0.0005486844,0.0001455816,0.0001565623,0.0001274917,0.0001780177,0.0004032405,0.0003147367,0.002150784],"category_scores_gemma":[0.0001857232,0.0001842731,0.0002372513,0.0001965556,0.0002028395,0.0004458861,0.0003914456,0.0005587166,0.0007193256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003088253,"about_ca_system_score_gemma":0.0001884475,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005103732,"about_ca_topic_score_gemma":0.001115411,"domain_scores_codex":[0.9998757,0.00001715277,0.000008607271,0.00002453981,0.00002175758,0.00005228369],"domain_scores_gemma":[0.9999418,0.0000107795,0.00001615245,0.00001044493,0.000007772947,0.00001302941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001521894,0.0001496096,0.000194576,0.0005317199,0.00004683048,0.000494116,0.0001662734,0.001440616,0.9803766,0.004984321,0.001011985,0.01045113],"study_design_scores_gemma":[0.00002638544,0.0003777226,0.0003878362,0.00001528739,0.00001613676,0.0001660292,0.00002134766,0.001795376,0.987701,0.0004022641,0.009075312,0.00001538955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9289036,0.003436662,0.03098704,0.0003565183,0.0002490896,0.0001214511,0.0005203924,0.0003510329,0.03507419],"genre_scores_gemma":[0.9900181,0.001625704,0.004101932,0.00007792142,0.00001314899,0.00002622403,0.0002020877,0.00002921627,0.003905665],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002150784,"threshold_uncertainty_score":0.007195055,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01199762719653153,"score_gpt":0.2212320416619235,"score_spread":0.209234414465392,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}