{"id":"W4235146587","doi":"10.1002/ange.201807181","title":"Metal‐Free and Redox‐Neutral Conversion of Organotrifluoroborates into Radicals Enabled by Visible Light","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Chemistry; Radical; Aryl; Reagent; Redox; Alkyl; Combinatorial chemistry; Photoredox catalysis; Photochemistry; Metal; Catalysis; Organic chemistry; Photocatalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001391215,0.0002487196,0.0004110573,0.00004766547,0.0001258029,0.00003363226,0.0003841746,0.0003128164,0.002253144],"category_scores_gemma":[0.0005229446,0.0002229768,0.0001008585,0.0002881691,0.0005371023,0.0001939799,0.0001815626,0.000263551,0.0000395786],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008863588,"about_ca_system_score_gemma":0.00006728086,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001631952,"about_ca_topic_score_gemma":0.000004998214,"domain_scores_codex":[0.9985178,0.00001310256,0.0003887382,0.0004514615,0.0002727623,0.0003561607],"domain_scores_gemma":[0.9985632,0.0001969133,0.0001683767,0.0005946052,0.0001543483,0.0003225758],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006634239,0.0001100406,0.0001392314,0.0001649407,0.00008320496,0.000003705052,0.0001357579,3.438872e-8,0.9200801,0.0000381704,0.07909467,0.00008378178],"study_design_scores_gemma":[0.0009810722,0.0000532757,0.000006857032,0.0000668091,0.00009235909,0.00001006349,0.00007085616,0.000007357514,0.9222604,0.001200662,0.07502434,0.0002259353],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.966508,0.001491427,0.00001916876,0.001114969,0.0000760538,0.0001217037,0.0000676135,0.0001342286,0.03046686],"genre_scores_gemma":[0.996091,0.0002652603,0.0006242877,0.0001805102,0.0002386834,0.00002230667,0.00009052151,0.00004301528,0.002444407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02958304,"threshold_uncertainty_score":0.998659,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007612580690883697,"score_gpt":0.2340024857192026,"score_spread":0.2263899050283189,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}