{"id":"W4235146587","doi":"10.1002/ange.201807181","title":"Metal‐Free and Redox‐Neutral Conversion of Organotrifluoroborates into Radicals Enabled by Visible Light","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Chemistry; Radical; Aryl; Reagent; Redox; Alkyl; Combinatorial chemistry; Photoredox catalysis; Photochemistry; Metal; Catalysis; Organic chemistry; Photocatalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001101827,0.0002507472,0.00009482108,0.0001503281,0.0001184052,0.0002095717,0.000245486,0.0002298034,0.001196771],"category_scores_gemma":[0.00008967071,0.0001309811,0.0001355112,0.0001208402,0.0001761062,0.0002450478,0.0001733091,0.0002895777,0.000260493],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002078972,"about_ca_system_score_gemma":0.0001722875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004871719,"about_ca_topic_score_gemma":0.001271686,"domain_scores_codex":[0.9999382,0.000006486118,0.00000430976,0.00001195913,0.00001588616,0.00002318455],"domain_scores_gemma":[0.9999593,0.000004619563,0.00001450863,0.000006077504,0.000007164165,0.000008229327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002696528,0.000006241752,0.00003363644,0.00003515219,0.00000261482,0.00002583776,0.00001261018,0.00004440925,0.9978694,0.0003073955,0.00004483727,0.001590845],"study_design_scores_gemma":[0.000005347405,0.0000421186,0.0001792886,0.000001774775,0.000003674156,0.00004284781,0.00000399673,0.0001458814,0.9982408,0.00002575614,0.001305869,0.00000255372],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853453,0.001494478,0.008743485,0.00009642589,0.0000434616,0.00002578656,0.0001756246,0.0001549958,0.003920386],"genre_scores_gemma":[0.9944425,0.0005894666,0.003011021,0.00001556221,0.000005510632,0.000009574751,0.00008716759,0.000013276,0.001825935],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001196771,"threshold_uncertainty_score":0.004003584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007612580690883697,"score_gpt":0.2340024857192026,"score_spread":0.2263899050283189,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}