{"id":"W4235158847","doi":"10.1002/ange.201408371","title":"Synthesis and Reactivity of a CAAC–Aminoborylene Adduct: A Hetero‐Allene or an Organoboron Isoelectronic with Singlet Carbenes","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":128,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Allene; Chemistry; Carbene; Adduct; Electrophile; Trimethylsilyl; Singlet state; Reactivity (psychology); Photochemistry; Molecule; Alkyl; Alkene; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001939125,0.000483708,0.0006743058,0.00005658196,0.000124445,0.00005320544,0.0003387581,0.0003183669,0.001102648],"category_scores_gemma":[0.0002293575,0.0003913462,0.00007783942,0.0001980101,0.0002779639,0.000266867,0.0001076533,0.0003010948,0.000004471268],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001420949,"about_ca_system_score_gemma":0.0001901506,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001702816,"about_ca_topic_score_gemma":0.0004366264,"domain_scores_codex":[0.9979116,0.00003546572,0.0003662749,0.0007632214,0.0003447182,0.0005787284],"domain_scores_gemma":[0.9981543,0.0002716288,0.0002664423,0.0008984254,0.0001234747,0.0002857608],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003596142,0.00029327,0.004619242,0.0005662142,0.0001053695,0.00001347462,0.000344388,9.755694e-7,0.9900243,0.0000105869,0.00009544649,0.003567103],"study_design_scores_gemma":[0.001051501,0.0002210299,0.00053232,0.0002022702,0.0001850131,0.000124501,0.0002875323,0.00001539625,0.9956397,0.0000222352,0.00118635,0.0005321884],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959961,0.0007401197,0.00001384022,0.0002027828,0.00002502522,0.0000774428,0.00005653387,0.0001707464,0.002717419],"genre_scores_gemma":[0.9984282,0.0003778699,0.0002930438,0.00009778954,0.0002541353,0.00003293169,0.00004203106,0.0001088526,0.000365161],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005615348,"threshold_uncertainty_score":0.9998538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01229245762374659,"score_gpt":0.2217027572432917,"score_spread":0.2094102996195451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}