{"id":"W4235163690","doi":"10.1002/ange.201502332","title":"Transition‐Metal‐Free α‐Arylation of Enolizable Aryl Ketones and Mechanistic Evidence for a Radical Process","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Centre in Green Chemistry and Catalysis","keywords":"Aryl; Chemistry; Transition metal; Halide; Process (computing); Base (topology); Combinatorial chemistry; Metal halides; Organic chemistry; Catalysis; Computer science; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002162888,0.000279514,0.00009594876,0.00008038288,0.000135629,0.0001622132,0.0002637632,0.0002485735,0.002461129],"category_scores_gemma":[0.0001639461,0.000115144,0.0001213808,0.00004747231,0.0002725259,0.0003228422,0.0001774353,0.0004631686,0.0004980009],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001370448,"about_ca_system_score_gemma":0.0001273426,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003795721,"about_ca_topic_score_gemma":0.0005147907,"domain_scores_codex":[0.9999186,0.00001506022,0.00000619002,0.00001182916,0.00001764202,0.00003073051],"domain_scores_gemma":[0.9999095,0.00002461332,0.00002191548,0.00001517614,0.00001393709,0.00001484943],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002530978,0.00004755989,0.0001555957,0.0001353434,0.00001331703,0.000414746,0.0000702235,0.0001990221,0.9946737,0.001766246,0.0002221876,0.002048973],"study_design_scores_gemma":[0.00003188527,0.0001630513,0.0004979635,0.000005077467,0.000009072606,0.0001806582,0.00001678085,0.0003207266,0.9963138,0.0001761529,0.002279405,0.000005591027],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9771527,0.001198457,0.01042098,0.0002851251,0.00008983923,0.00005733229,0.0002545438,0.0001220864,0.01041897],"genre_scores_gemma":[0.9974396,0.0002882619,0.0008544828,0.0000263865,0.000004384692,0.000007828032,0.00005488227,0.000005336992,0.00131882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002461129,"threshold_uncertainty_score":0.008233309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09169782377356389,"score_gpt":0.3355117984976506,"score_spread":0.2438139747240867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}