{"id":"W4235359300","doi":"10.1002/ange.201813431","title":"Size‐Control by Anion Templating in Mechanochemical Synthesis of Hemicucurbiturils in the Solid State","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Haridus- ja Teadusministeerium","keywords":"Template; Self-assembly; Chemistry; Ion; Solid-state; Solvent; Mechanochemistry; Nanotechnology; Combinatorial chemistry; Materials science; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000153303,0.0002143676,0.00009057124,0.00009721343,0.0001031777,0.0002318542,0.000153239,0.000145869,0.0008047187],"category_scores_gemma":[0.0001330348,0.0001100435,0.00009158924,0.00007415568,0.0002257282,0.0002472081,0.0001919879,0.0002747471,0.0002206855],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001810552,"about_ca_system_score_gemma":0.0001207049,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001948934,"about_ca_topic_score_gemma":0.0006069564,"domain_scores_codex":[0.999908,0.00001556757,0.000007978284,0.00002482936,0.00002355365,0.00002000617],"domain_scores_gemma":[0.9999073,0.00002033497,0.00003952799,0.00000966372,0.000009034092,0.00001408624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001845662,0.000009079212,0.00005194321,0.00002097203,0.000001441743,0.00002244404,0.00002166796,0.0001210556,0.9983875,0.0003511846,0.00002064383,0.0009736692],"study_design_scores_gemma":[0.000003730024,0.00004618212,0.0002151092,0.000001584442,0.000001364552,0.00001966857,0.000005081853,0.0006545747,0.9980945,0.00002756256,0.0009277687,0.00000293265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926306,0.0004679761,0.004406237,0.00006202985,0.00002619944,0.00001603077,0.00005060325,0.00008455115,0.002255891],"genre_scores_gemma":[0.9963807,0.000239201,0.002267363,0.00002128495,0.000008847683,0.00001348133,0.00002714718,0.00001750367,0.001024465],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008047187,"threshold_uncertainty_score":0.002692044,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006668838592890925,"score_gpt":0.22271714409707,"score_spread":0.2160483055041791,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}